Polyhalides as efficient and mild oxidants for oxidative carbene organocatalysis by radical processes

• المؤلفون الرئيسيون: Wu, Xingxing, Zhang, Yuexia, Wang, Yuhuang, Ke, Jie, Jeret, Martin, Reddi, Rambabu N., Yang, Song, Song, Bao-An, Chi, Robin Yonggui
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2017
• الموضوعات: Science::Chemistry; N-Heterocyclic Carbenes; Aldehydes
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/85610; http://hdl.handle.net/10220/43775

Simple and inexpensive polyhalides (CCl4 and C2Cl6 ) have been found to be effective and versatile oxidants in removing electrons from Breslow intermediates under N-heterocyclic carbene (NHC) catalysis. This oxidative reaction involves multiple single-electron-transfer (SET) processes and several ra...