Anodized Aluminum Oxide Templated Synthesis of Metal-Organic Frameworks Used as Membrane Reactors

The incorporation of metal–organic frameworks (MOFs) into membrane-shaped architectures is of great importance for practical applications. The currently synthesized MOF-based membranes show many disadvantages, such as poor compatibility, low dispersity, and instability, which severely limit their ut...

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Main Authors: Chen, Bo, Yu, Yifu, Wu, Xue-Jun, Zhao, Meiting, Ma, Qinglang, Chen, Junze, Sindoro, Melinda, Yang, Jian, Han, Shikui, Lu, Qipeng, Zhang, Hua
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2017
Subjects:
Online Access:https://hdl.handle.net/10356/86008
http://hdl.handle.net/10220/43919
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-860082020-06-01T10:01:33Z Anodized Aluminum Oxide Templated Synthesis of Metal-Organic Frameworks Used as Membrane Reactors Chen, Bo Yu, Yifu Wu, Xue-Jun Zhao, Meiting Ma, Qinglang Chen, Junze Sindoro, Melinda Yang, Jian Han, Shikui Lu, Qipeng Zhang, Hua School of Materials Science & Engineering Composite Membranes In Situ Synthesis The incorporation of metal–organic frameworks (MOFs) into membrane-shaped architectures is of great importance for practical applications. The currently synthesized MOF-based membranes show many disadvantages, such as poor compatibility, low dispersity, and instability, which severely limit their utility. Herein, we present a general, facile, and robust approach for the synthesis of MOF-based composite membranes through the in situ growth of MOF plates in the channels of anodized aluminum oxide (AAO) membranes. After being used as catalysis reactors, they exhibit high catalytic performance and stability in the Knoevenagel condensation reaction. The high catalytic performance might be attributed to the intrinsic structure of MOF-based composite membranes, which can remove the products from the reaction zone quickly, and prevent the aggregation and loss of catalysts during reaction and recycling process. MOE (Min. of Education, S’pore) 2017-10-17T08:36:51Z 2019-12-06T16:14:14Z 2017-10-17T08:36:51Z 2019-12-06T16:14:14Z 2017 Journal Article Yu, Y., Wu, X.-J., Zhao, M., Ma, Q., Chen, J., Chen, B., et al. (2017). Anodized Aluminum Oxide Templated Synthesis of Metal-Organic Frameworks Used as Membrane Reactors. Angewandte Chemie International Edition, 56(2), 578-581. 1433-7851 https://hdl.handle.net/10356/86008 http://hdl.handle.net/10220/43919 10.1002/anie.201610291 en Angewandte Chemie International Edition © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
topic Composite Membranes
In Situ Synthesis
spellingShingle Composite Membranes
In Situ Synthesis
Chen, Bo
Yu, Yifu
Wu, Xue-Jun
Zhao, Meiting
Ma, Qinglang
Chen, Junze
Sindoro, Melinda
Yang, Jian
Han, Shikui
Lu, Qipeng
Zhang, Hua
Anodized Aluminum Oxide Templated Synthesis of Metal-Organic Frameworks Used as Membrane Reactors
description The incorporation of metal–organic frameworks (MOFs) into membrane-shaped architectures is of great importance for practical applications. The currently synthesized MOF-based membranes show many disadvantages, such as poor compatibility, low dispersity, and instability, which severely limit their utility. Herein, we present a general, facile, and robust approach for the synthesis of MOF-based composite membranes through the in situ growth of MOF plates in the channels of anodized aluminum oxide (AAO) membranes. After being used as catalysis reactors, they exhibit high catalytic performance and stability in the Knoevenagel condensation reaction. The high catalytic performance might be attributed to the intrinsic structure of MOF-based composite membranes, which can remove the products from the reaction zone quickly, and prevent the aggregation and loss of catalysts during reaction and recycling process.
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Chen, Bo
Yu, Yifu
Wu, Xue-Jun
Zhao, Meiting
Ma, Qinglang
Chen, Junze
Sindoro, Melinda
Yang, Jian
Han, Shikui
Lu, Qipeng
Zhang, Hua
format Article
author Chen, Bo
Yu, Yifu
Wu, Xue-Jun
Zhao, Meiting
Ma, Qinglang
Chen, Junze
Sindoro, Melinda
Yang, Jian
Han, Shikui
Lu, Qipeng
Zhang, Hua
author_sort Chen, Bo
title Anodized Aluminum Oxide Templated Synthesis of Metal-Organic Frameworks Used as Membrane Reactors
title_short Anodized Aluminum Oxide Templated Synthesis of Metal-Organic Frameworks Used as Membrane Reactors
title_full Anodized Aluminum Oxide Templated Synthesis of Metal-Organic Frameworks Used as Membrane Reactors
title_fullStr Anodized Aluminum Oxide Templated Synthesis of Metal-Organic Frameworks Used as Membrane Reactors
title_full_unstemmed Anodized Aluminum Oxide Templated Synthesis of Metal-Organic Frameworks Used as Membrane Reactors
title_sort anodized aluminum oxide templated synthesis of metal-organic frameworks used as membrane reactors
publishDate 2017
url https://hdl.handle.net/10356/86008
http://hdl.handle.net/10220/43919
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