Synthesis and crystal structures of [Ph3PCH2PPh3]I2 dichloromethane disolvate and [Ph3PCH2PPh3](BI4)2

• Main Authors: Ganguly, Rakesh, Jevtovic, Violeta
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2017
• Subjects: Carbodi­phospho­rane; Crystal structure
• Online Access: https://hdl.handle.net/10356/86575; http://hdl.handle.net/10220/44044
• Institution: Nanyang Technological University

Reaction of BI3 with carbodi­phospho­rane, C(PPh3)2, gives a mixture of the dicationic compounds, methyl­enebis(tri­phenyl­phospho­nium) diiodide di­chloro­methane disolvate, C37H32P22+·2I−·2CH2Cl2 or [Ph3PCH2PPh3]I2·2CH2Cl2 (I), methyl­enebis(tri­phenyl­phospho­nium) bis­(tetra­iodo­borate), C37H32...