Green and rapid access to benzocoumarins via direct benzene construction through base-mediated formal [4+2] reaction and air oxidation

• Main Authors: Mou, Chengli, Zhu, Tingshun, Zheng, Pengcheng, Yang, Song, Song, Bao-An, Chi, Robin Yonggui
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2018
• 主題: Air Oxidative Aromatization; Arene Construction
• 在線閱讀: https://hdl.handle.net/10356/86648; http://hdl.handle.net/10220/45180
• 機構: Nanyang Technological University

Benzocoumarin is an important structural motif widely found in natural products and synthetic molecules. Traditional methods for the synthesis of benzocoumarins and their derivatives require multiple steps, typically with an intramolecular ester forming reaction to make the lactone ring as the last...