Monitoring the Wobbe Index of Natural Gas Using Fiber-Enhanced Raman Spectroscopy

• Main Authors: Sandfort, Vincenz, Trabold, Barbara M., Abdolvand, Amir, Bolwien, Carsten, Russell, Philip St. J., Wöllenstein, Jürgen, Palzer, Stefan
• Other Authors: School of Electrical and Electronic Engineering
• Format: Article
• Language: English
• Published: 2018
• Subjects: Raman Spectroscopy; Wobbe Index
• Online Access: https://hdl.handle.net/10356/87245; http://hdl.handle.net/10220/44340
• Institution: Nanyang Technological University

The fast and reliable analysis of the natural gas composition requires the simultaneous quantification of numerous gaseous components. To this end, fiber-enhanced Raman spectroscopy is a powerful tool to detect most components in a single measurement using a single laser source. However, practical issues such as detection limit, gas exchange time and background Raman signals from the fiber material still pose obstacles to utilizing the scheme in real-world settings. This paper compares the performance of two types of hollow-core photonic crystal fiber (PCF), namely photonic bandgap PCF and kagomé-style PCF, and assesses their potential for online determination of the Wobbe index. In contrast to bandgap PCF, kagomé-PCF allows for reliable detection of Raman-scattered photons even below 1200 cm−1, which in turn enables fast and comprehensive assessment of the natural gas quality of arbitrary mixtures.