Synthesis and electronic properties of novel 5,7-diazapentacene derivatives

A route to the synthesis of novel 5,7‐diazapentacenes and some preliminary studies on their properties is reported. A single crystal X‐ray diffraction study of the dihexyl derivative showed it had formed a dimer during the analysis. The materials possess lower lying frontier orbitals than pentacene,...

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Main Authors: Lunchev, Andrey V., Morris, Samuel A., Ganguly, Rakesh, Grimsdale, Andrew Clive
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2019
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Online Access:https://hdl.handle.net/10356/87492
http://hdl.handle.net/10220/47660
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-874922023-02-28T19:34:14Z Synthesis and electronic properties of novel 5,7-diazapentacene derivatives Lunchev, Andrey V. Morris, Samuel A. Ganguly, Rakesh Grimsdale, Andrew Clive School of Materials Science & Engineering School of Physical and Mathematical Sciences Arenes Synthetic Methods DRNTU::Science::Chemistry A route to the synthesis of novel 5,7‐diazapentacenes and some preliminary studies on their properties is reported. A single crystal X‐ray diffraction study of the dihexyl derivative showed it had formed a dimer during the analysis. The materials possess lower lying frontier orbitals than pentacene, and may have potential applications in organic electronic devices. This synthetic method may be applicable to the synthesis of other azaacenes. MOE (Min. of Education, S’pore) Accepted version 2019-02-13T07:36:38Z 2019-12-06T16:43:03Z 2019-02-13T07:36:38Z 2019-12-06T16:43:03Z 2019 Journal Article Lunchev, A. V., Morris, S. A., Ganguly, R., & Grimsdale, A. C. (2019). Synthesis and electronic properties of novel 5,7-diazapentacene derivatives. Chemistry - A European Journal, 25(7), 1819-1823. doi:10.1002/chem.201805466 0947-6539 https://hdl.handle.net/10356/87492 http://hdl.handle.net/10220/47660 10.1002/chem.201805466 en Chemistry - A European Journal © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved. This paper was published in Chemistry - A European Journal and is made available with permission of Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. 6 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Arenes
Synthetic Methods
DRNTU::Science::Chemistry
spellingShingle Arenes
Synthetic Methods
DRNTU::Science::Chemistry
Lunchev, Andrey V.
Morris, Samuel A.
Ganguly, Rakesh
Grimsdale, Andrew Clive
Synthesis and electronic properties of novel 5,7-diazapentacene derivatives
description A route to the synthesis of novel 5,7‐diazapentacenes and some preliminary studies on their properties is reported. A single crystal X‐ray diffraction study of the dihexyl derivative showed it had formed a dimer during the analysis. The materials possess lower lying frontier orbitals than pentacene, and may have potential applications in organic electronic devices. This synthetic method may be applicable to the synthesis of other azaacenes.
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Lunchev, Andrey V.
Morris, Samuel A.
Ganguly, Rakesh
Grimsdale, Andrew Clive
format Article
author Lunchev, Andrey V.
Morris, Samuel A.
Ganguly, Rakesh
Grimsdale, Andrew Clive
author_sort Lunchev, Andrey V.
title Synthesis and electronic properties of novel 5,7-diazapentacene derivatives
title_short Synthesis and electronic properties of novel 5,7-diazapentacene derivatives
title_full Synthesis and electronic properties of novel 5,7-diazapentacene derivatives
title_fullStr Synthesis and electronic properties of novel 5,7-diazapentacene derivatives
title_full_unstemmed Synthesis and electronic properties of novel 5,7-diazapentacene derivatives
title_sort synthesis and electronic properties of novel 5,7-diazapentacene derivatives
publishDate 2019
url https://hdl.handle.net/10356/87492
http://hdl.handle.net/10220/47660
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