Synthesis and electronic properties of novel 5,7-diazapentacene derivatives
A route to the synthesis of novel 5,7‐diazapentacenes and some preliminary studies on their properties is reported. A single crystal X‐ray diffraction study of the dihexyl derivative showed it had formed a dimer during the analysis. The materials possess lower lying frontier orbitals than pentacene,...
Saved in:
Main Authors: | , , , |
---|---|
Other Authors: | |
Format: | Article |
Language: | English |
Published: |
2019
|
Subjects: | |
Online Access: | https://hdl.handle.net/10356/87492 http://hdl.handle.net/10220/47660 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Institution: | Nanyang Technological University |
Language: | English |
id |
sg-ntu-dr.10356-87492 |
---|---|
record_format |
dspace |
spelling |
sg-ntu-dr.10356-874922023-02-28T19:34:14Z Synthesis and electronic properties of novel 5,7-diazapentacene derivatives Lunchev, Andrey V. Morris, Samuel A. Ganguly, Rakesh Grimsdale, Andrew Clive School of Materials Science & Engineering School of Physical and Mathematical Sciences Arenes Synthetic Methods DRNTU::Science::Chemistry A route to the synthesis of novel 5,7‐diazapentacenes and some preliminary studies on their properties is reported. A single crystal X‐ray diffraction study of the dihexyl derivative showed it had formed a dimer during the analysis. The materials possess lower lying frontier orbitals than pentacene, and may have potential applications in organic electronic devices. This synthetic method may be applicable to the synthesis of other azaacenes. MOE (Min. of Education, S’pore) Accepted version 2019-02-13T07:36:38Z 2019-12-06T16:43:03Z 2019-02-13T07:36:38Z 2019-12-06T16:43:03Z 2019 Journal Article Lunchev, A. V., Morris, S. A., Ganguly, R., & Grimsdale, A. C. (2019). Synthesis and electronic properties of novel 5,7-diazapentacene derivatives. Chemistry - A European Journal, 25(7), 1819-1823. doi:10.1002/chem.201805466 0947-6539 https://hdl.handle.net/10356/87492 http://hdl.handle.net/10220/47660 10.1002/chem.201805466 en Chemistry - A European Journal © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved. This paper was published in Chemistry - A European Journal and is made available with permission of Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. 6 p. application/pdf |
institution |
Nanyang Technological University |
building |
NTU Library |
continent |
Asia |
country |
Singapore Singapore |
content_provider |
NTU Library |
collection |
DR-NTU |
language |
English |
topic |
Arenes Synthetic Methods DRNTU::Science::Chemistry |
spellingShingle |
Arenes Synthetic Methods DRNTU::Science::Chemistry Lunchev, Andrey V. Morris, Samuel A. Ganguly, Rakesh Grimsdale, Andrew Clive Synthesis and electronic properties of novel 5,7-diazapentacene derivatives |
description |
A route to the synthesis of novel 5,7‐diazapentacenes and some preliminary studies on their properties is reported. A single crystal X‐ray diffraction study of the dihexyl derivative showed it had formed a dimer during the analysis. The materials possess lower lying frontier orbitals than pentacene, and may have potential applications in organic electronic devices. This synthetic method may be applicable to the synthesis of other azaacenes. |
author2 |
School of Materials Science & Engineering |
author_facet |
School of Materials Science & Engineering Lunchev, Andrey V. Morris, Samuel A. Ganguly, Rakesh Grimsdale, Andrew Clive |
format |
Article |
author |
Lunchev, Andrey V. Morris, Samuel A. Ganguly, Rakesh Grimsdale, Andrew Clive |
author_sort |
Lunchev, Andrey V. |
title |
Synthesis and electronic properties of novel 5,7-diazapentacene derivatives |
title_short |
Synthesis and electronic properties of novel 5,7-diazapentacene derivatives |
title_full |
Synthesis and electronic properties of novel 5,7-diazapentacene derivatives |
title_fullStr |
Synthesis and electronic properties of novel 5,7-diazapentacene derivatives |
title_full_unstemmed |
Synthesis and electronic properties of novel 5,7-diazapentacene derivatives |
title_sort |
synthesis and electronic properties of novel 5,7-diazapentacene derivatives |
publishDate |
2019 |
url |
https://hdl.handle.net/10356/87492 http://hdl.handle.net/10220/47660 |
_version_ |
1759853114584727552 |