Bay-region functionalisation of Ar-BIAN ligands and their use within highly absorptive cationic iridium(III) dyes

• Main Authors: Kamrul Hasan, Wang, Jingyi, Pal, Amlan K., Hierlinger, Claus, Guerchais, Véronique, Soo, Han Sen, García, Felipe, Zysman-Colman, Eli
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2018
• Subjects: Ar-BIAN Ligands; DRNTU::Science::Chemistry; Heteroleptic Iridium Complexes
• Online Access: https://hdl.handle.net/10356/87793; http://hdl.handle.net/10220/46814
• Institution: Nanyang Technological University

We report the synthesis, UV-vis absorption, electrochemical characterisation, and DFT studies of five panchromatic, heteroleptic iridium complexes (four of which are new) supported by Ar-BIAN ligands. In particular, the synthesis of an ester-functionalised Ar-BIAN ligand was carried out by a mechano...