水的结构和反常物性 = Perspective : structures and properties of liquid water

自从Bernal-Fowler-Pauling在1933~1935年间提出氢质子在两个氧原子之间的非对称等价位置以THz的频率自发往复隧穿后,液态水的结构尤其是水分子的近邻配位数目一直是学界关注的焦点。尽管水分子的刚性或柔性偶极子相互作用表述、纳晶非晶混相结构或均相涨落模型等假说已逐渐成为认知主流,但定量破解水在外场作用下所呈现的各种反常物性的进展依然缓慢。譬如,浮冰、复冰、超滑、热水速冻等现象的机理及内在关联仍有待系统深入研究。本文旨在尝试解读当前关注焦点和介绍最新研究进展的同时,融合连续介质论、分子时空论、质子量子论和氢键弛豫极化论并强调从传统的分子“偶极子-偶极子”到“氢键(O:H—O)...

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Bibliographic Details
Main Authors: 李蕾 Li, Lei, 姚闯 Yao, Chuang, 张希 Zhang, Xi, 黄勇力 Huang, Yongli, 马增胜 Ma, Zengsheng, 孙长庆 Sun, Changqing
Other Authors: School of Electrical and Electronic Engineering
Format: Article
Language:English
Published: 2019
Subjects:
Online Access:https://hdl.handle.net/10356/89875
http://hdl.handle.net/10220/49442
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Institution: Nanyang Technological University
Language: English
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