Selective photocatalytic C–C bond cleavage under ambient conditions with earth abundant vanadium complexes

• Main Authors: Gazi, Sarifuddin, Ganguly, Rakesh, Putra Moeljadi, Adhitya Mangala, Hirao, Hajime, Soo, Han Sen, Ng, Wilson Kwok Hung
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2018
• 主題: Chemical Bonds; DRNTU::Science::Chemistry; Vanadium Compounds
• 在線閱讀: https://hdl.handle.net/10356/89930; http://hdl.handle.net/10220/46441
• 機構: Nanyang Technological University

Selective C–C bond cleavage under ambient conditions is a challenging chemical transformation that can be a valuable tool for organic syntheses and macromolecular disassembly. Herein, we show that base metal vanadium photocatalysts can harvest visible light to effect the chemoselective C–C bond clea...