Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing
An unexpected “kinked” N-heteroacene with a slipped two-dimensional ladder-like packing feature is produced from the conventional condensation reaction. The as-obtained compound [2,2′]bi(5,12-bis(TIPS)piperazin-3-one[2,3-b]phenazine) (2BPP) consists of two identical backbones (5,12-bis(TIPS)piperazi...
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sg-ntu-dr.10356-902022023-07-14T15:52:54Z Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing Zhang, Jing Wang, Chengyuan Long, Guankui Aratani, Naoki Yamada, Hiroko Zhang, Qichun School of Materials Science & Engineering School of Physical and Mathematical Sciences Carrier Transport Hole Mobility DRNTU::Engineering::Materials An unexpected “kinked” N-heteroacene with a slipped two-dimensional ladder-like packing feature is produced from the conventional condensation reaction. The as-obtained compound [2,2′]bi(5,12-bis(TIPS)piperazin-3-one[2,3-b]phenazine) (2BPP) consists of two identical backbones (5,12-bis(TIPS)piperazin-3-one[2,3-b]phenazine), which are fused together through a C[double bond, length as m-dash]C double bond and two intramolecular H-bonds. A study on the charge carrier transport indicates that a 2BPP single crystal has a hole mobility up to 0.3 cm2 V−1 s−1, while theoretical calculations suggest that this compound might possess potential well-balanced ambipolar charge-transport characteristics. NRF (Natl Research Foundation, S’pore) MOE (Min. of Education, S’pore) Published version 2018-12-24T04:52:56Z 2019-12-06T17:43:00Z 2018-12-24T04:52:56Z 2019-12-06T17:43:00Z 2016 Journal Article Zhang, J., Wang, C., Long, G., Aratani, N., Yamada, H., & Zhang, Q. (2016). Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing. Chemical Science, 7(2), 1309-1313. doi:10.1039/C5SC03604F 2041-6520 https://hdl.handle.net/10356/90202 http://hdl.handle.net/10220/47187 10.1039/C5SC03604F en Chemical Science © 2016 The Author(s) (published by Royal Society of Chemistry). This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. 5 p. application/pdf |
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Carrier Transport Hole Mobility DRNTU::Engineering::Materials Zhang, Jing Wang, Chengyuan Long, Guankui Aratani, Naoki Yamada, Hiroko Zhang, Qichun Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing |
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An unexpected “kinked” N-heteroacene with a slipped two-dimensional ladder-like packing feature is produced from the conventional condensation reaction. The as-obtained compound [2,2′]bi(5,12-bis(TIPS)piperazin-3-one[2,3-b]phenazine) (2BPP) consists of two identical backbones (5,12-bis(TIPS)piperazin-3-one[2,3-b]phenazine), which are fused together through a C[double bond, length as m-dash]C double bond and two intramolecular H-bonds. A study on the charge carrier transport indicates that a 2BPP single crystal has a hole mobility up to 0.3 cm2 V−1 s−1, while theoretical calculations suggest that this compound might possess potential well-balanced ambipolar charge-transport characteristics. |
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School of Materials Science & Engineering |
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School of Materials Science & Engineering Zhang, Jing Wang, Chengyuan Long, Guankui Aratani, Naoki Yamada, Hiroko Zhang, Qichun |
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Zhang, Jing Wang, Chengyuan Long, Guankui Aratani, Naoki Yamada, Hiroko Zhang, Qichun |
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Zhang, Jing |
title |
Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing |
title_short |
Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing |
title_full |
Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing |
title_fullStr |
Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing |
title_full_unstemmed |
Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing |
title_sort |
fusing n-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing |
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2018 |
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https://hdl.handle.net/10356/90202 http://hdl.handle.net/10220/47187 |
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