Polymeric rotaxane constructed from the inclusion complex of β-cyclodextrin and 4,4'-dipyridine by coordination with nickel(II) ions

Nanometer-sized supramolecular assemblies created by the simple inclusion complexation of host cyclodextrins (CDs) and guest molecules have attracted more and more attention in recent years because of their...

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Bibliographic Details
Main Authors: Liu, Yu, Zhao, Yanli, Zhang, Heng Yi, Song, Hai Bin
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Published: 2011
Subjects:
Online Access:https://hdl.handle.net/10356/93945
http://hdl.handle.net/10220/6952
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Institution: Nanyang Technological University
Description
Summary:Nanometer-sized supramolecular assemblies created by the simple inclusion complexation of host cyclodextrins (CDs) and guest molecules have attracted more and more attention in recent years because of their potential to serve as molecular devices and molecular machines, as well as functional materials.[1–4] Indeed, CDs can be threaded on a polymer chain to form a polyrotaxane and extended to molecular tubes through the cross-linking of adjacent CD units in a polyrotaxane.