Supramolecular polypseudorotaxane with conjugated polyazomethine prepared directly from two inclusion complexes of β-cyclodextrin with tolidine and phthaldehyde

Supramolecular polypseudorotaxane with conjugated polyazomethine prepared directly from two inclusion complexes of β-cyclodextrin with tolidine and phthaldehyde

The supramolecular polypseudorotaxane (3) with π-conjugated polyazomethine is directly...

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Bibliographic Details
Main Authors:	Zhang, Xin Zheng, Liu, Yu, Zhao, Yanli, Zhang, Heng Yi, Li, Xiao Yun, Liang, Peng, Xu, Jing Jun
Format:	Article
Published:	2011
Subjects:	DRNTU::Science::Biological sciences::Biochemistry
Online Access:	https://hdl.handle.net/10356/94180 http://hdl.handle.net/10220/6995
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Institution:	Nanyang Technological University

Description
Summary:	The supramolecular polypseudorotaxane (3) with π-conjugated polyazomethine is directly synthesized by the polycondensation of two simple inclusion complexes of β-cyclodextrin/o-tolidine (1) and β-cyclodextrin/p-phthaldehyde (2) and is comprehensively characterized by NMR, FTIR, circular dichroism spectra, powder X-ray diffraction, thermogravimetric (TG) and differential thermal analysis (DTA), scanning electron microscopy (SEM), and scanning tunneling microscopy (STM) both in solution and in the solid state. The results obtained have revealed linear microstructure of polypseudorotaxane 3 and different photophysical behavior as compared with the π-conjugated polyazomethine backbone (4). The present investigations prove a simple method for preparing supramolecular polypseudorotaxane by different complexes, which possess the potential to serve as molecular devices/machines and optical materials.