Power factor enhancement for few-layered graphene films by molecular attachments

In this work, we prepared few-layered graphene (FLG) films and investigated their thermoelectric properties. It was found that pristine FLG films showed a low thermopower of ~40 μV/K. We further processed these FLG films by attaching them with 1,1′-azobis(cyanocyclohexane) or 1,3,6,8-pyrenetetrasulf...

全面介紹

Saved in:
書目詳細資料
Main Authors: Sim, Daohao, Liu, Dayong, Dong, Xiaochen, Xiao, Ni, Li, Sean, Zhao, Yang, Li, Lain-Jong, Yan, Qingyu, Hng, Huey Hoon
其他作者: School of Materials Science & Engineering
格式: Article
語言:English
出版: 2012
主題:
在線閱讀:https://hdl.handle.net/10356/94711
http://hdl.handle.net/10220/7451
標簽: 添加標簽
沒有標簽, 成為第一個標記此記錄!
機構: Nanyang Technological University
語言: English
實物特徵
總結:In this work, we prepared few-layered graphene (FLG) films and investigated their thermoelectric properties. It was found that pristine FLG films showed a low thermopower of ~40 μV/K. We further processed these FLG films by attaching them with 1,1′-azobis(cyanocyclohexane) or 1,3,6,8-pyrenetetrasulfonic acid. The thermopower of FLG films with attached molecules increased to above ~180 μV/K. Such enhancement in the thermopower led to an increase in their power factor by more than 4.5 times. Theoretical investigation indicated that a potential difference can be introduced between the outer layer and inner layer of FLG films upon molecule attachments. Simulation of the thermopower based on Kubo’s formula provided qualitative support to our experimental results.