Nickel–thiolate complex catalyst assembled in one step in water for solar H2 production

Nickel–thiolate complex catalyst assembled in one step in water for solar H2 production

We report the use of a simple complex assembled from Ni(II) salt and 2-mecaptoethanol in one step in water as the efficient catalyst in a molecular hydrogen system which can be sensitized by a low-cost xanthene dye, Erythrosin B. An excellent quantum efficiency of 24.5% is attained at 460 nm. This s...

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Main Authors: Hong, Jindui, Zheng, Jianwei, Huang, Zhiyan, Zhou, Jianrong Steve, Xu, Rong, Zhang, Wei
Other Authors: School of Chemical and Biomedical Engineering
Format: Article
Language:English
Published: 2012
Subjects:
DRNTU::Engineering
Online Access:https://hdl.handle.net/10356/94965
http://hdl.handle.net/10220/8167
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-949652023-12-29T06:46:44Z Nickel–thiolate complex catalyst assembled in one step in water for solar H2 production Hong, Jindui Zheng, Jianwei Huang, Zhiyan Zhou, Jianrong Steve Xu, Rong Zhang, Wei School of Chemical and Biomedical Engineering DRNTU::Engineering We report the use of a simple complex assembled from Ni(II) salt and 2-mecaptoethanol in one step in water as the efficient catalyst in a molecular hydrogen system which can be sensitized by a low-cost xanthene dye, Erythrosin B. An excellent quantum efficiency of 24.5% is attained at 460 nm. This simple system is expected to contribute toward the development of economical and environmentally benign solar hydrogen production systems. Accepted version 2012-05-29T06:41:51Z 2019-12-06T19:05:31Z 2012-05-29T06:41:51Z 2019-12-06T19:05:31Z 2011 2011 Journal Article Zhang, W., Hong, J., Zheng, J., Huang, Z., Zhou, J. & Xu, R. (2011). Nickel–Thiolate Complex Catalyst Assembled in One Step in Water for Solar H2 Production. Journal of the American Chemical Society, 133(51), 20680–20683. https://hdl.handle.net/10356/94965 http://hdl.handle.net/10220/8167 10.1021/ja208555h 164749 en Journal of the American chemical society © 2011 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of the American Chemical Society, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [DOI: http://dx.doi.org/10.1021/ja208555h]. 4 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic DRNTU::Engineering
spellingShingle DRNTU::Engineering
Hong, Jindui
Zheng, Jianwei
Huang, Zhiyan
Zhou, Jianrong Steve
Xu, Rong
Zhang, Wei
Nickel–thiolate complex catalyst assembled in one step in water for solar H2 production
description We report the use of a simple complex assembled from Ni(II) salt and 2-mecaptoethanol in one step in water as the efficient catalyst in a molecular hydrogen system which can be sensitized by a low-cost xanthene dye, Erythrosin B. An excellent quantum efficiency of 24.5% is attained at 460 nm. This simple system is expected to contribute toward the development of economical and environmentally benign solar hydrogen production systems.
author2 School of Chemical and Biomedical Engineering
author_facet School of Chemical and Biomedical Engineering
Hong, Jindui
Zheng, Jianwei
Huang, Zhiyan
Zhou, Jianrong Steve
Xu, Rong
Zhang, Wei
format Article
author Hong, Jindui
Zheng, Jianwei
Huang, Zhiyan
Zhou, Jianrong Steve
Xu, Rong
Zhang, Wei
author_sort Hong, Jindui
title Nickel–thiolate complex catalyst assembled in one step in water for solar H2 production
title_short Nickel–thiolate complex catalyst assembled in one step in water for solar H2 production
title_full Nickel–thiolate complex catalyst assembled in one step in water for solar H2 production
title_fullStr Nickel–thiolate complex catalyst assembled in one step in water for solar H2 production
title_full_unstemmed Nickel–thiolate complex catalyst assembled in one step in water for solar H2 production
title_sort nickel–thiolate complex catalyst assembled in one step in water for solar h2 production
publishDate 2012
url https://hdl.handle.net/10356/94965
http://hdl.handle.net/10220/8167
_version_ 1787136497124638720

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