Sorption characteristics and mechanisms of oxyanions and oxyhalides having different molecular properties on Mg/Al layered double hydroxide nanoparticles
The sorption ability of fast-coprecipitated and hydrothermally-treated Mg/Al layered double hydroxide nanoparticles (FCHT-LDH) for various oxyhalides and oxyanions was evaluated. Interactions of oxyhalide such as monovalent bromate or oxyanions such as divalent chromate and divalent vanadate with FC...
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sg-ntu-dr.10356-954492020-06-01T10:26:30Z Sorption characteristics and mechanisms of oxyanions and oxyhalides having different molecular properties on Mg/Al layered double hydroxide nanoparticles Goh, Kok Hui Lim, Teik-Thye Banas, Agnieszka Dong, Zhili School of Materials Science & Engineering DRNTU::Engineering::Materials The sorption ability of fast-coprecipitated and hydrothermally-treated Mg/Al layered double hydroxide nanoparticles (FCHT-LDH) for various oxyhalides and oxyanions was evaluated. Interactions of oxyhalide such as monovalent bromate or oxyanions such as divalent chromate and divalent vanadate with FCHT-LDH were investigated using a combination of macroscopic (batch sorption/desorption studies and electrophoretic mobility (EM) measurements) and microscopic techniques (CHNS/O, XRD, FTIR, XPS, and EXAFS analyses). The sorption studies on various oxyanions and oxyhalides suggested that their sorption characteristics on FCHT-LDH were largely governed by their ionic potentials and molecular structures. Oxyanions which have ionic potentials higher than 7 nm−1 were found to be more readily sorbed by FCHT-LDH than oxyhalides with ionic potentials lower than 5 nm−1. The results obtained also demonstrated that trigonal pyramid oxyhalides showed a lower degree of specificity for FCHT-LDH than the tetrahedral coordinated oxyanions. From the macroscopic and microscopic studies, monovalent oxyhalide sorption on FCHT-LDH was postulated to occur mainly via anion exchange mechanism with subsequent formation of outer-sphere surface complexes. For polyvalent oxyanion sorption on FCHT-LDH, the mechanisms were possibly associated with both anion exchange and ligand exchange reactions, resulting in the coexistence of outer-sphere and inner-sphere surface complexes. Accepted version 2012-12-12T06:40:05Z 2019-12-06T19:15:06Z 2012-12-12T06:40:05Z 2019-12-06T19:15:06Z 2010 2010 Journal Article Goh, K. H., Lim, T. T., Banas, A., & Dong, Z. (2010). Sorption characteristics and mechanisms of oxyanions and oxyhalides having different molecular properties on Mg/Al layered double hydroxide nanoparticles. Journal of Hazardous Materials, 179(1-3), 818-827. 0304-3894 https://hdl.handle.net/10356/95449 http://hdl.handle.net/10220/8869 10.1016/j.jhazmat.2010.03.077 en Journal of hazardous materials © 2010 Elsevier B.V. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of Hazardous Materials, Elsevier B.V. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [DOI:dx.doi.org/10.1016/j.jhazmat.2010.03.077]. application/pdf |
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DRNTU::Engineering::Materials Goh, Kok Hui Lim, Teik-Thye Banas, Agnieszka Dong, Zhili Sorption characteristics and mechanisms of oxyanions and oxyhalides having different molecular properties on Mg/Al layered double hydroxide nanoparticles |
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The sorption ability of fast-coprecipitated and hydrothermally-treated Mg/Al layered double hydroxide nanoparticles (FCHT-LDH) for various oxyhalides and oxyanions was evaluated. Interactions of oxyhalide such as monovalent bromate or oxyanions such as divalent chromate and divalent vanadate with FCHT-LDH were investigated using a combination of macroscopic (batch sorption/desorption studies and electrophoretic mobility (EM) measurements) and microscopic techniques (CHNS/O, XRD, FTIR, XPS, and EXAFS analyses). The sorption studies on various oxyanions and oxyhalides suggested that their sorption characteristics on FCHT-LDH were largely governed by their ionic potentials and molecular structures. Oxyanions which have ionic potentials higher than 7 nm−1 were found to be more readily sorbed by FCHT-LDH than oxyhalides with ionic potentials lower than 5 nm−1. The results obtained also demonstrated that trigonal pyramid oxyhalides showed a lower degree of specificity for FCHT-LDH than the tetrahedral coordinated oxyanions. From the macroscopic and microscopic studies, monovalent oxyhalide sorption on FCHT-LDH was postulated to occur mainly via anion exchange mechanism with subsequent formation of outer-sphere surface complexes. For polyvalent oxyanion sorption on FCHT-LDH, the mechanisms were possibly associated with both anion exchange and ligand exchange reactions, resulting in the coexistence of outer-sphere and inner-sphere surface complexes. |
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School of Materials Science & Engineering |
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School of Materials Science & Engineering Goh, Kok Hui Lim, Teik-Thye Banas, Agnieszka Dong, Zhili |
format |
Article |
author |
Goh, Kok Hui Lim, Teik-Thye Banas, Agnieszka Dong, Zhili |
author_sort |
Goh, Kok Hui |
title |
Sorption characteristics and mechanisms of oxyanions and oxyhalides having different molecular properties on Mg/Al layered double hydroxide nanoparticles |
title_short |
Sorption characteristics and mechanisms of oxyanions and oxyhalides having different molecular properties on Mg/Al layered double hydroxide nanoparticles |
title_full |
Sorption characteristics and mechanisms of oxyanions and oxyhalides having different molecular properties on Mg/Al layered double hydroxide nanoparticles |
title_fullStr |
Sorption characteristics and mechanisms of oxyanions and oxyhalides having different molecular properties on Mg/Al layered double hydroxide nanoparticles |
title_full_unstemmed |
Sorption characteristics and mechanisms of oxyanions and oxyhalides having different molecular properties on Mg/Al layered double hydroxide nanoparticles |
title_sort |
sorption characteristics and mechanisms of oxyanions and oxyhalides having different molecular properties on mg/al layered double hydroxide nanoparticles |
publishDate |
2012 |
url |
https://hdl.handle.net/10356/95449 http://hdl.handle.net/10220/8869 |
_version_ |
1681058715829010432 |