W(CO)5(L)-catalyzed cyclization of α-alkynyl-β-dicarbonyl derivatives : synthesis of methylenelactones, furans, and methylenecyclopentanes

W(CO)5(L)-Catalyzed cyclization of α-alkynyl-β-keto acids, keto esters, and diketones provides methylenelactones, furans, and methylenecyclopentanes via 5-exo-dig cyclization. Also, the present approach can be further applied to 5-endo-dig cyclization.

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Main Authors: Meng, Xiangjian., Kim, Sunggak.
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/96037
http://hdl.handle.net/10220/11881
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-960372020-03-07T12:31:25Z W(CO)5(L)-catalyzed cyclization of α-alkynyl-β-dicarbonyl derivatives : synthesis of methylenelactones, furans, and methylenecyclopentanes Meng, Xiangjian. Kim, Sunggak. School of Physical and Mathematical Sciences W(CO)5(L)-Catalyzed cyclization of α-alkynyl-β-keto acids, keto esters, and diketones provides methylenelactones, furans, and methylenecyclopentanes via 5-exo-dig cyclization. Also, the present approach can be further applied to 5-endo-dig cyclization. 2013-07-18T06:43:39Z 2019-12-06T19:24:46Z 2013-07-18T06:43:39Z 2019-12-06T19:24:46Z 2012 2012 Journal Article Meng, X., & Kim, S. (2012). W(CO)5(L)-Catalyzed Cyclization of α-Alkynyl-β-dicarbonyl Derivatives: Synthesis of Methylenelactones, Furans, and Methylenecyclopentanes. Synlett, 23(13), 1960-1964. https://hdl.handle.net/10356/96037 http://hdl.handle.net/10220/11881 10.1055/s-0032-1316536 en Synlett © 2012 Georg Thieme Verlag Stuttgart · New York.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
description W(CO)5(L)-Catalyzed cyclization of α-alkynyl-β-keto acids, keto esters, and diketones provides methylenelactones, furans, and methylenecyclopentanes via 5-exo-dig cyclization. Also, the present approach can be further applied to 5-endo-dig cyclization.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Meng, Xiangjian.
Kim, Sunggak.
format Article
author Meng, Xiangjian.
Kim, Sunggak.
spellingShingle Meng, Xiangjian.
Kim, Sunggak.
W(CO)5(L)-catalyzed cyclization of α-alkynyl-β-dicarbonyl derivatives : synthesis of methylenelactones, furans, and methylenecyclopentanes
author_sort Meng, Xiangjian.
title W(CO)5(L)-catalyzed cyclization of α-alkynyl-β-dicarbonyl derivatives : synthesis of methylenelactones, furans, and methylenecyclopentanes
title_short W(CO)5(L)-catalyzed cyclization of α-alkynyl-β-dicarbonyl derivatives : synthesis of methylenelactones, furans, and methylenecyclopentanes
title_full W(CO)5(L)-catalyzed cyclization of α-alkynyl-β-dicarbonyl derivatives : synthesis of methylenelactones, furans, and methylenecyclopentanes
title_fullStr W(CO)5(L)-catalyzed cyclization of α-alkynyl-β-dicarbonyl derivatives : synthesis of methylenelactones, furans, and methylenecyclopentanes
title_full_unstemmed W(CO)5(L)-catalyzed cyclization of α-alkynyl-β-dicarbonyl derivatives : synthesis of methylenelactones, furans, and methylenecyclopentanes
title_sort w(co)5(l)-catalyzed cyclization of α-alkynyl-β-dicarbonyl derivatives : synthesis of methylenelactones, furans, and methylenecyclopentanes
publishDate 2013
url https://hdl.handle.net/10356/96037
http://hdl.handle.net/10220/11881
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