Graphene oxide organogel electrolyte for quasi solid dye sensitized solar cells

Low concentration, as low as 0.4 wt.% graphene oxide organogels is reported for different organic solvents. The gelation of organic solvents at exceedingly low concentrations opens the door for the implementation of graphene oxides based electrolytes in various electrochemical applications. Here we...

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Bibliographic Details
Main Authors: Gun, Jenny, Kulkarni, Sneha A., Xiu, Wang, Batabyal, Sudip Kumar, Sladkevich, Sergey, Prikhodchenko, Petr V., Gutkin, Vitaly, Lev, Ovadia
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/96163
http://hdl.handle.net/10220/10857
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Institution: Nanyang Technological University
Language: English
Description
Summary:Low concentration, as low as 0.4 wt.% graphene oxide organogels is reported for different organic solvents. The gelation of organic solvents at exceedingly low concentrations opens the door for the implementation of graphene oxides based electrolytes in various electrochemical applications. Here we demonstrate the use of acetonitrile–graphene oxide (GO) gel containing iodide/triiodide as a quasi-solid electrolyte for dye sensitized solar cells (DSCs). Electrochemical impedance studies reveal that the mass transfer barrier is not adversely affected by the presence of the minute amount of GO gel former. The achieved energy conversion efficiency (η) for the device without GO and with 1% GO gel electrolytes is 6.9% and 7.5% respectively under one sun illumination.