Finely dispersed single-walled carbon nanotubes for polysaccharide hydrogels

Here we demonstrate a polysaccharide hydrogel reinforced with finely dispersed single-walled carbon nanotubes (SWNTs) using biocompatible dispersants O-carboxymethylchitosan (OC) and chondroitin sulfate A (CS-A) as a structural support. Both of the dispersants can disperse SWNTs in aqueous solutions...

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Bibliographic Details
Main Authors: Yan, Liang Yu, Chen, Hailan, Li, Peng, Kim, Dong-Hwan, Chan, Mary Bee Eng
Other Authors: School of Chemical and Biomedical Engineering
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/96245
http://hdl.handle.net/10220/10238
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Institution: Nanyang Technological University
Language: English
Description
Summary:Here we demonstrate a polysaccharide hydrogel reinforced with finely dispersed single-walled carbon nanotubes (SWNTs) using biocompatible dispersants O-carboxymethylchitosan (OC) and chondroitin sulfate A (CS-A) as a structural support. Both of the dispersants can disperse SWNTs in aqueous solutions and hydrogel matrix as individual tubes or small bundles. Additionally, we have found that compressive modulus and strain of the hydrogels reinforced with SWNTs were enhanced as much as two times by the addition of a few weight percent of SWNTs. Moreover, the SWNT-incorporated hydrogels exhibited lower impedance and higher charge capacity than the alginate/dispersant hydrogel without SWNTs. The OC and the CS-A demonstrated much higher reinforcing enhancement than a commercially available dispersant, sodium dodecyl sulfate. Combined with the experimental data on the mechanical and electrical properties, the biocompatibility of OC and CS-A can provide the possibility of biomedical application of the SWNT-reinforced hydrogels.