Reactivity of a tin(II) (Iminophosphinoyl)(thiophosphinoyl)methanediide complex toward sulfur : synthesis and 119Sn Mössbauer spectroscopic studies of [{(μ-S)SnC(PPh2═NSiMe3)(PPh2═S)}3Sn(μ3-S)]
Reaction of [(PPh2═NSiMe3)(PPh2═S)CSn:]2 (1) with elemental sulfur in toluene afforded [{(μ-S)tiebar above startSnIVC(PPh2═NSiMe3)(PPh2═S)}3SnII(μ3-Stiebar above end)] (2) and [CH2(PPh2═NSiMe3)(PPh2═S)] (3). Compound 2 comprises a SnIIS moiety coordinated with the SnIV and S atoms of a trimeric 2-st...
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Main Authors: | , , , , , , |
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Other Authors: | |
Format: | Article |
Language: | English |
Published: |
2013
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Online Access: | https://hdl.handle.net/10356/96723 http://hdl.handle.net/10220/11593 |
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Institution: | Nanyang Technological University |
Language: | English |