Formation of 1D hierarchical structures composed of Ni3S2 nanosheets on CNTs backbone for supercapacitors and photocatalytic H2 production
One-dimensional (1D) hierarchical structures composed of Ni3S2 nanosheets grown on carbon nanotube (CNT) backbone (denoted as CNT@Ni3S2) are fabricated by a rational multi-step transformation route. The first step involves coating the CNT backbone with a layer of silica to form CNT@SiO2, which serve...
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| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/96789 http://hdl.handle.net/10220/10370 |
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| Summary: | One-dimensional (1D) hierarchical structures composed of Ni3S2 nanosheets grown on carbon nanotube (CNT) backbone (denoted as CNT@Ni3S2) are fabricated by a rational multi-step transformation route. The first step involves coating the CNT backbone with a layer of silica to form CNT@SiO2, which serves as the substrate for the growth of nickel silicate (NiSilicate) nanosheets in the second step to form CNT@SiO2@NiSilicate core-double shell 1D structures. Finally the as-formed CNT@SiO2@NiSilicate 1D structures are converted into CNT-supported Ni3S2 nanosheets via hydrothermal treatment in the presence of Na2S. Simultaneously the intermediate silica layer is eliminated during the hydrothermal treatment, leading to the formation of CNT@Ni3S2 nanostructures. Because of the unique hybrid nano-architecture, the as-prepared 1D hierarchical structure is shown to exhibit excellent performance in both supercapacitors and photocatalytic H2 production. |
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