Synthesis of organic silane microcapsules for self-healing corrosion resistant polymer coatings
Hydrolysable organic silane, i.e. 1H,1H,2H,2H-perfluorooctyl triethoxysilane (POTS), was carefully selected and microencapsulated as healing agent via in situ polymerization in an oil-in-water emulsion. The microcapsule size was adjustable via changing agitation rate for various coating systems. POT...
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Main Authors: | , , |
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Other Authors: | |
Format: | Article |
Language: | English |
Published: |
2013
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Online Access: | https://hdl.handle.net/10356/96805 http://hdl.handle.net/10220/13184 |
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Institution: | Nanyang Technological University |
Language: | English |
Summary: | Hydrolysable organic silane, i.e. 1H,1H,2H,2H-perfluorooctyl triethoxysilane (POTS), was carefully selected and microencapsulated as healing agent via in situ polymerization in an oil-in-water emulsion. The microcapsule size was adjustable via changing agitation rate for various coating systems. POTS microcapsules were incorporated into epoxy resin and coated on a steel substrate to form a corrosion resistant organic coating. The corrosion test in the salt solution demonstrated the good corrosion resistance of the self-healing coating compared to the control sample. Additional analysis revealed that the corrosion prohibition functionality was realised by an autonomous self-healing mechanism of the encapsulated POTS hydrolysed with water upon scratch. |
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