Synthesis, crystal structure, and optical properties of a three-dimensional quaternary Hg–In–S–Cl chalcohalide : Hg7InS6Cl5

Synthesis, crystal structure, and optical properties of a three-dimensional quaternary Hg–In–S–Cl chalcohalide : Hg7InS6Cl5

A crystalline three-dimensional (3D) quaternary chalcohalide, Hg7InS6Cl5 (1), has been synthesized through a solid-state reaction under medium temperature. It is the first example in the family of the Hg–IIIA–Q–X (Q = S, Se, Te; X = F, Cl, Br, I) systems. Compound 1 features a 3D network and has an...

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Bibliographic Details
Main Authors: Liu, Yi, Wei, Fengxia, Yeo, Sing Ning, Lee, Fu Min, Yan, Qingyu, Hng, Huey Hoon, Ma, Jan, Zhang, Qichun, Kloc, Christian
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/96914
http://hdl.handle.net/10220/11592
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Institution: Nanyang Technological University
Language: English
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Summary:A crystalline three-dimensional (3D) quaternary chalcohalide, Hg7InS6Cl5 (1), has been synthesized through a solid-state reaction under medium temperature. It is the first example in the family of the Hg–IIIA–Q–X (Q = S, Se, Te; X = F, Cl, Br, I) systems. Compound 1 features a 3D network and has an optical band gap of 2.54 eV.

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