11.3% efficient planar Si-PEDOT : PSS hybrid solar cell with a thin interfacial oxide
Hybrid solar cells are fabricated based on heterojunction between planar n-type Si and a p-type polymer, poly (3,4-ethylene-dioxythiophene): polystyrenesulfonate (PEDOT: PSS). The effect of hydrogen-terminated (H-Si) and oxide-terminated (SiOx-Si) Si surface on the cell performance are investigated....
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Main Authors: | , , , , , |
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Other Authors: | |
Format: | Conference or Workshop Item |
Language: | English |
Published: |
2013
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Online Access: | https://hdl.handle.net/10356/97367 http://hdl.handle.net/10220/13170 |
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Institution: | Nanyang Technological University |
Language: | English |
Summary: | Hybrid solar cells are fabricated based on heterojunction between planar n-type Si and a p-type polymer, poly (3,4-ethylene-dioxythiophene): polystyrenesulfonate (PEDOT: PSS). The effect of hydrogen-terminated (H-Si) and oxide-terminated (SiOx-Si) Si surface on the cell performance are investigated. Compared to cells with H-Si surface that exhibits a power conversion efficiency (PCE) of 0.04%, the PCE of the cells with SiOx-Si surface is boosted significantly to 11.3%. It is also found that the SiOx-Si cell exhibits a much better diode rectifying behavior and the SiOx-Si surface bonding results in a favorable band alignment in the Si/PEDOT interface for photo-excited carrier separation. |
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