11.3% efficient planar Si-PEDOT : PSS hybrid solar cell with a thin interfacial oxide

Hybrid solar cells are fabricated based on heterojunction between planar n-type Si and a p-type polymer, poly (3,4-ethylene-dioxythiophene): polystyrenesulfonate (PEDOT: PSS). The effect of hydrogen-terminated (H-Si) and oxide-terminated (SiOx-Si) Si surface on the cell performance are investigated....

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Bibliographic Details
Main Authors: He, Lining, Jiang, Changyun, Wang, Hao, Lei, Hong, Lai, Donny, Rusli
Other Authors: School of Electrical and Electronic Engineering
Format: Conference or Workshop Item
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/97367
http://hdl.handle.net/10220/13170
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Institution: Nanyang Technological University
Language: English
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Summary:Hybrid solar cells are fabricated based on heterojunction between planar n-type Si and a p-type polymer, poly (3,4-ethylene-dioxythiophene): polystyrenesulfonate (PEDOT: PSS). The effect of hydrogen-terminated (H-Si) and oxide-terminated (SiOx-Si) Si surface on the cell performance are investigated. Compared to cells with H-Si surface that exhibits a power conversion efficiency (PCE) of 0.04%, the PCE of the cells with SiOx-Si surface is boosted significantly to 11.3%. It is also found that the SiOx-Si cell exhibits a much better diode rectifying behavior and the SiOx-Si surface bonding results in a favorable band alignment in the Si/PEDOT interface for photo-excited carrier separation.