Catalytic asymmetric [4+2] annulation initiated by an Aza-Rauhut-Currier reaction : facile entry to highly functionalized tetrahydropyridines

Catalytic asymmetric [4+2] annulation initiated by an Aza-Rauhut-Currier reaction : facile entry to highly functionalized tetrahydropyridines

Under control: The first example of chiral amino phosphine catalysts for the title reaction between vinyl ketones and N-sulfonyl-1-aza-1,3-dienes has been developed. Under ambient conditions, this protocol provides straightforward access to densely functionalized, enantioenriched tetrahydropyridines...

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Main Authors: Shi, Zugui, Yu, Peiyuan, Loh, Teck-Peng, Zhong, Guofu
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/98453
http://hdl.handle.net/10220/12444
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-984532020-03-07T12:34:47Z Catalytic asymmetric [4+2] annulation initiated by an Aza-Rauhut-Currier reaction : facile entry to highly functionalized tetrahydropyridines Shi, Zugui Yu, Peiyuan Loh, Teck-Peng Zhong, Guofu School of Physical and Mathematical Sciences Under control: The first example of chiral amino phosphine catalysts for the title reaction between vinyl ketones and N-sulfonyl-1-aza-1,3-dienes has been developed. Under ambient conditions, this protocol provides straightforward access to densely functionalized, enantioenriched tetrahydropyridines with high levels of sterecontrol in good to excellent yields. 2013-07-29T04:43:56Z 2019-12-06T19:55:23Z 2013-07-29T04:43:56Z 2019-12-06T19:55:23Z 2012 2012 Journal Article Shi, Z., Yu, P., Loh, T. P., & Zhong, G. (2012). Catalytic Asymmetric [4+2] Annulation Initiated by an Aza-Rauhut-Currier Reaction: Facile Entry to Highly Functionalized Tetrahydropyridines. Angewandte Chemie International Edition, 51(31), 7825-7829. 1433-7851 https://hdl.handle.net/10356/98453 http://hdl.handle.net/10220/12444 10.1002/anie.201203316 en Angewandte chemie international edition © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
description Under control: The first example of chiral amino phosphine catalysts for the title reaction between vinyl ketones and N-sulfonyl-1-aza-1,3-dienes has been developed. Under ambient conditions, this protocol provides straightforward access to densely functionalized, enantioenriched tetrahydropyridines with high levels of sterecontrol in good to excellent yields.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Shi, Zugui
Yu, Peiyuan
Loh, Teck-Peng
Zhong, Guofu
format Article
author Shi, Zugui
Yu, Peiyuan
Loh, Teck-Peng
Zhong, Guofu
spellingShingle Shi, Zugui
Yu, Peiyuan
Loh, Teck-Peng
Zhong, Guofu
Catalytic asymmetric [4+2] annulation initiated by an Aza-Rauhut-Currier reaction : facile entry to highly functionalized tetrahydropyridines
author_sort Shi, Zugui
title Catalytic asymmetric [4+2] annulation initiated by an Aza-Rauhut-Currier reaction : facile entry to highly functionalized tetrahydropyridines
title_short Catalytic asymmetric [4+2] annulation initiated by an Aza-Rauhut-Currier reaction : facile entry to highly functionalized tetrahydropyridines
title_full Catalytic asymmetric [4+2] annulation initiated by an Aza-Rauhut-Currier reaction : facile entry to highly functionalized tetrahydropyridines
title_fullStr Catalytic asymmetric [4+2] annulation initiated by an Aza-Rauhut-Currier reaction : facile entry to highly functionalized tetrahydropyridines
title_full_unstemmed Catalytic asymmetric [4+2] annulation initiated by an Aza-Rauhut-Currier reaction : facile entry to highly functionalized tetrahydropyridines
title_sort catalytic asymmetric [4+2] annulation initiated by an aza-rauhut-currier reaction : facile entry to highly functionalized tetrahydropyridines
publishDate 2013
url https://hdl.handle.net/10356/98453
http://hdl.handle.net/10220/12444
_version_ 1681037073845321728

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