A vanadyl complex grafted to periodic mesoporous organosilica : a green catalyst for selective hydroxylation of benzene to phenol

A vanadyl complex grafted to periodic mesoporous organosilica : a green catalyst for selective hydroxylation of benzene to phenol

Selective benzene hydroxylation: A periodic mesoporous organosilica embedded with a vanadyl(IV) acetylacetonate complex has been synthesized through a co-condensation method. This system is a catalyst for direct hydroxylation of benzene to phenol, presenting a selectivity of 100 % towards the phenol...

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Main Authors: Borah, Parijat, Ma, Xing, Nguyen, Kim Truc, Zhao, Yanli
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/98509
http://hdl.handle.net/10220/12441
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-985092020-06-01T10:26:48Z A vanadyl complex grafted to periodic mesoporous organosilica : a green catalyst for selective hydroxylation of benzene to phenol Borah, Parijat Ma, Xing Nguyen, Kim Truc Zhao, Yanli School of Materials Science & Engineering School of Physical and Mathematical Sciences Selective benzene hydroxylation: A periodic mesoporous organosilica embedded with a vanadyl(IV) acetylacetonate complex has been synthesized through a co-condensation method. This system is a catalyst for direct hydroxylation of benzene to phenol, presenting a selectivity of 100 % towards the phenol formation as well as an excellent catalytic recyclability (see scheme). 2013-07-29T04:34:43Z 2019-12-06T19:56:21Z 2013-07-29T04:34:43Z 2019-12-06T19:56:21Z 2012 2012 Journal Article Borah, P., Ma, X., Nguyen, K. T., & Zhao, Y. (2012). A Vanadyl Complex Grafted to Periodic Mesoporous Organosilica: A Green Catalyst for Selective Hydroxylation of Benzene to Phenol. Angewandte Chemie International Edition, 51(31), 7756-7761. 1433-7851 https://hdl.handle.net/10356/98509 http://hdl.handle.net/10220/12441 10.1002/anie.201203275 en Angewandte chemie international edition © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
description Selective benzene hydroxylation: A periodic mesoporous organosilica embedded with a vanadyl(IV) acetylacetonate complex has been synthesized through a co-condensation method. This system is a catalyst for direct hydroxylation of benzene to phenol, presenting a selectivity of 100 % towards the phenol formation as well as an excellent catalytic recyclability (see scheme).
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Borah, Parijat
Ma, Xing
Nguyen, Kim Truc
Zhao, Yanli
format Article
author Borah, Parijat
Ma, Xing
Nguyen, Kim Truc
Zhao, Yanli
spellingShingle Borah, Parijat
Ma, Xing
Nguyen, Kim Truc
Zhao, Yanli
A vanadyl complex grafted to periodic mesoporous organosilica : a green catalyst for selective hydroxylation of benzene to phenol
author_sort Borah, Parijat
title A vanadyl complex grafted to periodic mesoporous organosilica : a green catalyst for selective hydroxylation of benzene to phenol
title_short A vanadyl complex grafted to periodic mesoporous organosilica : a green catalyst for selective hydroxylation of benzene to phenol
title_full A vanadyl complex grafted to periodic mesoporous organosilica : a green catalyst for selective hydroxylation of benzene to phenol
title_fullStr A vanadyl complex grafted to periodic mesoporous organosilica : a green catalyst for selective hydroxylation of benzene to phenol
title_full_unstemmed A vanadyl complex grafted to periodic mesoporous organosilica : a green catalyst for selective hydroxylation of benzene to phenol
title_sort vanadyl complex grafted to periodic mesoporous organosilica : a green catalyst for selective hydroxylation of benzene to phenol
publishDate 2013
url https://hdl.handle.net/10356/98509
http://hdl.handle.net/10220/12441
_version_ 1681056921908412416

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