From soft self-healing gels to stiff films in suckerin-based materials through modulation of crosslink density and β-sheet content

Suckerins are block-copolymer-like structural proteins constituting the building blocks of the strong squid sucker-ring teeth. Here, recombinant suckerin-19 is processed into biomaterials spanning a wide range of elasticity, from very soft hydrogels to stiff films with elastic modulus in the gigapas...

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Bibliographic Details
Main Authors: Ding, Dawei, Guerette, Paul A., Fu, Jing, Zhang, Lihong, Irvine, Scott Alexander, Miserez, Ali
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2015
Online Access:https://hdl.handle.net/10356/98566
http://hdl.handle.net/10220/38596
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Institution: Nanyang Technological University
Language: English
Description
Summary:Suckerins are block-copolymer-like structural proteins constituting the building blocks of the strong squid sucker-ring teeth. Here, recombinant suckerin-19 is processed into biomaterials spanning a wide range of elasticity, from very soft hydrogels to stiff films with elastic modulus in the gigapascal range. The elasticity is controlled by the interplay between the β-sheet content and induced di-tyrosine crosslinking.