Observation of clusters in Re60Fe30Al10 alloys and the associated magnetic properties

Magnetic properties and microstructure of melt-spun ribbons of RE60Fe30Al10 alloys with RE = Nd, Sm, Dy, Gd and Y were studied in detail. High coercivity values in the range of MA m−1 were observed at low temperatures for amorphous ribbons. Presence of Fe-rich clusters and nanoscale rare-earth cryst...

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Bibliographic Details
Main Authors: Ding, Jun, Dong, Zhili, White, Timothy John, Kong, H. Z., Wang, L., Li, Y.
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2012
Subjects:
Online Access:https://hdl.handle.net/10356/98731
http://hdl.handle.net/10220/8296
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Institution: Nanyang Technological University
Language: English
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Summary:Magnetic properties and microstructure of melt-spun ribbons of RE60Fe30Al10 alloys with RE = Nd, Sm, Dy, Gd and Y were studied in detail. High coercivity values in the range of MA m−1 were observed at low temperatures for amorphous ribbons. Presence of Fe-rich clusters and nanoscale rare-earth crystallites in the amorphous matrix in the ribbons were revealed by high-resolution transmission electron microscopy studies. The magnetic transition temperatures were estimated experimentally and compared with fitting results based on the cluster ferromagnetism model (Wang L et al 2001 Phys. Rev. B 64 214410). Possible mechanisms for the magnetic behaviour observed due to the presence of Fe-rich magnetic clusters are discussed.