Low symmetry phase in (001) BiFeO3 epitaxial constrained thin films

The lattice of (001)-oriented BiFeO3 epitaxial thin film has been identified by synchrotron x-ray diffraction. By choosing proper scattering zones containing the fixed (001) reflection, we have...

Full description

Saved in:
Bibliographic Details
Main Authors: Shirane, G., Xu, Guangyong, Hiraka, H., Li, Jiefang, Wang, Junling, Viehland, D.
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2011
Subjects:
Online Access:https://hdl.handle.net/10356/98739
http://hdl.handle.net/10220/6909
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English
Description
Summary:The lattice of (001)-oriented BiFeO3 epitaxial thin film has been identified by synchrotron x-ray diffraction. By choosing proper scattering zones containing the fixed (001) reflection, we have shown that low-symmetry phases similar to a MA phase exist in the thin film at room temperature. These results demonstrate a change in phase stability from rhombohedral in bulk single crystals, to a modified monoclinic structure in epitaxial thin films.