Synthesis and characterization of a singlet delocalized 2,4-diimino-1,3-disilacyclobutanediyl and a silylenylsilaimine

The synthesis and characterization of a singlet delocalized 2,4-diimino-1,3-disilacyclobutanediyl, [LSi(μ-CNAr)2SiL] (2, L: PhC(NtBu)2, Ar: 2,6-iPr2C6H3), and a silylenylsilaimine, [LSi([DOUBLE BOND]NAr)[BOND]SiL] (3), are described. The reaction of three equivalents of the disilylene [LSi[BOND]SiL]...

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Bibliographic Details
Main Authors: Zhang, Shu-Hua, Xi, Hong Wei, Lim, Kok Hwa, Meng, Qingyong, Huang, Ming-Bao, So, Cheuk-Wai
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/99505
http://hdl.handle.net/10220/12995
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Institution: Nanyang Technological University
Language: English