The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water
The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally.
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sg-ntu-dr.10356-995642023-02-28T20:03:00Z The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water Lee, Jia Ying Fan, Wai Yip Mak, Garvin Kar Hang Leong, Weng Kee School of Physical and Mathematical Sciences The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally. MOE (Min. of Education, S’pore) Accepted version 2013-11-07T07:11:54Z 2019-12-06T20:08:57Z 2013-11-07T07:11:54Z 2019-12-06T20:08:57Z 2012 2012 Journal Article Lee, J. Y., Fan, W. Y., Mak, K. H. G., & Leong, W. K. (2013). The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water. Journal of Organometallic Chemistry, 724, 275-280. 0022-328X https://hdl.handle.net/10356/99564 http://hdl.handle.net/10220/17390 10.1016/j.jorganchem.2012.11.030 en Journal of organometallic chemistry © 2012 Elsevier B.V. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of organometallic chemistry, Elsevier B.V. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1016/j.jorganchem.2012.11.030]. application/pdf |
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The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Lee, Jia Ying Fan, Wai Yip Mak, Garvin Kar Hang Leong, Weng Kee |
| format |
Article |
| author |
Lee, Jia Ying Fan, Wai Yip Mak, Garvin Kar Hang Leong, Weng Kee |
| spellingShingle |
Lee, Jia Ying Fan, Wai Yip Mak, Garvin Kar Hang Leong, Weng Kee The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water |
| author_sort |
Lee, Jia Ying |
| title |
The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water |
| title_short |
The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water |
| title_full |
The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water |
| title_fullStr |
The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water |
| title_full_unstemmed |
The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water |
| title_sort |
formation of aldehydes from the photochemically activated reaction of cp*ir(co)(cl)(ch2r) complexes with water |
| publishDate |
2013 |
| url |
https://hdl.handle.net/10356/99564 http://hdl.handle.net/10220/17390 |
| _version_ |
1759857746326323200 |