Singular behavior of fluctuations in a relaxation process
Carrying out explicitly the computation in a paradigmatic model of non-interacting systems, the Gaussian model, we show the existence of a singular point in the probability distribution P(M) of an extensive variable M. Interpreting P(M) as a thermodynamic potential of a dual system obtained from the...
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sg-ntu-dr.10356-996722023-02-28T19:41:37Z Singular behavior of fluctuations in a relaxation process Corberi, Federico Gonnella, Giuseppe Piscitelli, Antonio School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Crystallography Carrying out explicitly the computation in a paradigmatic model of non-interacting systems, the Gaussian model, we show the existence of a singular point in the probability distribution P(M) of an extensive variable M. Interpreting P(M) as a thermodynamic potential of a dual system obtained from the original one by applying a constraint, we discuss how the non-analytical point of P(M) is the counterpart of a phase-transition in the companion system. We show the generality of such mechanism by considering both the system in equilibrium or in non-equilibrium state following a temperature quench. Accepted version 2015-05-26T00:43:05Z 2019-12-06T20:10:03Z 2015-05-26T00:43:05Z 2019-12-06T20:10:03Z 2014 2014 Journal Article Corberi, F., Gonnella, G., & Piscitelli, A. (2014). Singular behavior of fluctuations in a relaxation process. Journal of non-crystalline solids, 407, 51-56. https://hdl.handle.net/10356/99672 http://hdl.handle.net/10220/25670 186354 en Journal of non-crystalline solids © 2014 Elsevier. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of non-crystalline solids, Elsevier. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1016/j.jnoncrysol.2014.07.039]. application/pdf |
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DRNTU::Science::Chemistry::Crystallography Corberi, Federico Gonnella, Giuseppe Piscitelli, Antonio Singular behavior of fluctuations in a relaxation process |
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Carrying out explicitly the computation in a paradigmatic model of non-interacting systems, the Gaussian model, we show the existence of a singular point in the probability distribution P(M) of an extensive variable M. Interpreting P(M) as a thermodynamic potential of a dual system obtained from the original one by applying a constraint, we discuss how the non-analytical point of P(M) is the counterpart of a phase-transition in the companion system. We show the generality of such mechanism by considering both the system in equilibrium or in non-equilibrium state following a temperature quench. |
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School of Physical and Mathematical Sciences |
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School of Physical and Mathematical Sciences Corberi, Federico Gonnella, Giuseppe Piscitelli, Antonio |
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Article |
author |
Corberi, Federico Gonnella, Giuseppe Piscitelli, Antonio |
author_sort |
Corberi, Federico |
title |
Singular behavior of fluctuations in a relaxation process |
title_short |
Singular behavior of fluctuations in a relaxation process |
title_full |
Singular behavior of fluctuations in a relaxation process |
title_fullStr |
Singular behavior of fluctuations in a relaxation process |
title_full_unstemmed |
Singular behavior of fluctuations in a relaxation process |
title_sort |
singular behavior of fluctuations in a relaxation process |
publishDate |
2015 |
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https://hdl.handle.net/10356/99672 http://hdl.handle.net/10220/25670 |
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1759855301451841536 |