“Clean reaction” strategy to approach a stable, green Heptatwistacene containing a single terminal pyrene unit

“Clean reaction” strategy to approach a stable, green Heptatwistacene containing a single terminal pyrene unit

Let's twist again: A “clean reaction” strategy based on thermally eliminating lactam bridges from a soluble acene precursor through a retro-Diels–Alder reaction gives a new, stable, green heptatwistacene (see structure). The molecule has a twist angle of 23.49°, is very stable even in air, and...

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Main Authors: Malliakas, Christos D., Kanatzidis, Mercouri G., Xiao, Jinchong, Liu, Yi, Zhou, Feng, Li, Gang, Su, Haibin, Wudl, Fred, Zhang, Qichun
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/99758
http://hdl.handle.net/10220/12984
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-997582020-06-01T10:01:40Z “Clean reaction” strategy to approach a stable, green Heptatwistacene containing a single terminal pyrene unit Malliakas, Christos D. Kanatzidis, Mercouri G. Xiao, Jinchong Liu, Yi Zhou, Feng Li, Gang Su, Haibin Wudl, Fred Zhang, Qichun School of Materials Science & Engineering Let's twist again: A “clean reaction” strategy based on thermally eliminating lactam bridges from a soluble acene precursor through a retro-Diels–Alder reaction gives a new, stable, green heptatwistacene (see structure). The molecule has a twist angle of 23.49°, is very stable even in air, and has an optical band gap of 1.82 eV. 2013-08-05T03:38:12Z 2019-12-06T20:11:05Z 2013-08-05T03:38:12Z 2019-12-06T20:11:05Z 2012 2012 Journal Article Xiao, J., Malliakas, C. D., Liu, Y., Zhou, F., Li, G., Su, H., Kanatzidis, M. G., Wudl, F.,& Zhang, Q. (2012). “Clean Reaction” Strategy to Approach a Stable, Green Heptatwistacene Containing a Single Terminal Pyrene Unit. Chemistry - An Asian Journal, 7(4), 672-675. 1861-4728 https://hdl.handle.net/10356/99758 http://hdl.handle.net/10220/12984 10.1002/asia.201100910 en Chemistry - an Asian journal
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
description Let's twist again: A “clean reaction” strategy based on thermally eliminating lactam bridges from a soluble acene precursor through a retro-Diels–Alder reaction gives a new, stable, green heptatwistacene (see structure). The molecule has a twist angle of 23.49°, is very stable even in air, and has an optical band gap of 1.82 eV.
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Malliakas, Christos D.
Kanatzidis, Mercouri G.
Xiao, Jinchong
Liu, Yi
Zhou, Feng
Li, Gang
Su, Haibin
Wudl, Fred
Zhang, Qichun
format Article
author Malliakas, Christos D.
Kanatzidis, Mercouri G.
Xiao, Jinchong
Liu, Yi
Zhou, Feng
Li, Gang
Su, Haibin
Wudl, Fred
Zhang, Qichun
spellingShingle Malliakas, Christos D.
Kanatzidis, Mercouri G.
Xiao, Jinchong
Liu, Yi
Zhou, Feng
Li, Gang
Su, Haibin
Wudl, Fred
Zhang, Qichun
“Clean reaction” strategy to approach a stable, green Heptatwistacene containing a single terminal pyrene unit
author_sort Malliakas, Christos D.
title “Clean reaction” strategy to approach a stable, green Heptatwistacene containing a single terminal pyrene unit
title_short “Clean reaction” strategy to approach a stable, green Heptatwistacene containing a single terminal pyrene unit
title_full “Clean reaction” strategy to approach a stable, green Heptatwistacene containing a single terminal pyrene unit
title_fullStr “Clean reaction” strategy to approach a stable, green Heptatwistacene containing a single terminal pyrene unit
title_full_unstemmed “Clean reaction” strategy to approach a stable, green Heptatwistacene containing a single terminal pyrene unit
title_sort “clean reaction” strategy to approach a stable, green heptatwistacene containing a single terminal pyrene unit
publishDate 2013
url https://hdl.handle.net/10356/99758
http://hdl.handle.net/10220/12984
_version_ 1681058133712044032

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