Co(II)-tricarboxylate metal–organic frameworks constructed from solvent-directed assembly for CO2 adsorption

• Main Authors: Li, Pei-Zhou, Wang, Xiao-Jun, Li, Yongxin, Zhang, Quan, Tan, Desmond Rong He, Lim, Wei Quan, Ganguly, Rakesh, Zhao, Yanli
• Other Authors: School of Materials Science & Engineering
• Format: Article
• Language: English
• Published: 2013
• Subjects: DRNTU::Engineering::Materials
• Online Access: https://hdl.handle.net/10356/99770; http://hdl.handle.net/10220/17398
• Institution: Nanyang Technological University

A series of Co(II)-tricarboxylate metal–organic frameworks (MOFs), {Co3O(HBTC)2(H2O)(DMF)}n (1), {Co2(BTC)Cl(DEF)3}n (2), {Co3O(BTB)2(DMF)·2(N(CH3)2)·(H2O)}n (3), and {Co3(HCOO)(BTB)2 (DEF)·(N(C2H5)2)}n (4) (BTC = 1,3,5-benzenetricarboxylate, BTB = 4,4′,4″-benzene-1,3,5-triyltribenzoate, DMF = N,N′-...