Synthesis, characterization, and nonvolatile ternary memory behavior of a larger heteroacene with nine linearly fused rings and two different heteroatoms

To achieve ultrahigh density memory devices with the capacity of 3n or larger, organic materials with multilevel stable states are highly desirable. Here, we reported a novel larger stable heteroacene, 2,3,13,14-tetradecyloxy-5,11,16,22-tetraaza-6,10,17,21-tetrachloro-7,9,18,20-tetraoxa-8,19-dicyano...

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Bibliographic Details
Main Authors: Gu, Pei-Yang, Zhou, Feng, Gao, Junkuo, Li, Gang, Wang, Chengyuan, Xu, Qing-Feng, Zhang, Qichun, Lu, Jian-Mei
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2013
Subjects:
Online Access:https://hdl.handle.net/10356/99807
http://hdl.handle.net/10220/17594
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Institution: Nanyang Technological University
Language: English
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Summary:To achieve ultrahigh density memory devices with the capacity of 3n or larger, organic materials with multilevel stable states are highly desirable. Here, we reported a novel larger stable heteroacene, 2,3,13,14-tetradecyloxy-5,11,16,22-tetraaza-6,10,17,21-tetrachloro-7,9,18,20-tetraoxa-8,19-dicyanoenneacene (CDPzN), which has two different types of heteroatoms (O and N) and nine linearly fused rings. The sandwich-structure memory devices based on CDPzN exhibited excellent ternary memory behaviors with high ON2/ON1/OFF current ratios of 106.3/104.3/1 and good stability for these three states.