Catalytic Dehalogenation of Highly Chlorinated Benzenes and Aroclors Using PdCl2(dppf) and NaBH4: Efficiency, Selectivity, and Base Support

Catalytic Dehalogenation of Highly Chlorinated Benzenes and Aroclors Using PdCl2(dppf) and NaBH4: Efficiency, Selectivity, and Base Support

Journal of Organic Chemistry

Saved in:

Bibliographic Details
Main Authors:	Lassová, L., Lee, H.K., Hor, T.S.A.
Other Authors:	CHEMISTRY
Format:	Article
Published:	2014
Online Access:	http://scholarbank.nus.edu.sg/handle/10635/93239
Tags:	Add Tag No Tags, Be the first to tag this record!
Institution:	National University of Singapore

Similar Items

[PdCl2(dppfO2-O,O')]: A simple palladium(II) complex with a rare tetrahedral structure
by: Yeo, J.S.L., et al.
Published: (2014)

Ferrocenyl phosphine mobility, positional isomerism and NMR fluxionality in triangular palladium sulfide aggregates. Crystal and molecular structures of [Pd3Cl2(η2-dppf)(μ-dppf)(μ 3-S)2] and [Pd3Cl(η2-dppf)2(PPh3)(μ 3-S)2]X [X = Cl or NO3, dppf = ...
by: Yeo, J.S.L., et al.
Published: (2014)

Investigation of the effect of dopant on catalytic performance of cobalt-oxide powders synthesised by gel casting technique for hydrolysis of NaBH4
by: Lee, Jing Hao
Published: (2015)

Heteropolymetallic aggregates from [Pd2(dppf)2(μ-S)2]. Bonding and structural analysis of [Ag2Pd2Cl2(dppf)2(μ 3-S)2]·4CH2Cl2 [dppf = Fe(C5H4PPh2)2] - A flat {Pd2S2} core with two AgCl 'tails'
by: Li, G., et al.
Published: (2014)

Catalytic reductive dechlorination of chlorinated benzenes with nanoscale Pd/Fe particles : kinetics, mechanism, and influences of aqueous matrix
by: Zhu, Bao Wei
Published: (2011)

ISOLATION AND CHARACTERIZATION OF DEHALOGENATORS THAT DETOXIFY POLYBROMINATED DIPHENYL ETHERS AND CHLORINATED ALKANES
by: DING CHANG
Published: (2020)

Isolation of Geraniol From Rhodinol by Using PDC Reagent NaHSO3 and NaBH4
by: Priatmoko, Priatmooko
Published: (2010)

Chloride substitution of [CpRu(dppf)Cl] with sulfur-containing ligands
by: Lu, X.L., et al.
Published: (2014)

Synthesis and characterization of cobalt oxide by aqueous gel-casting technique as catalyst precursor for NaBH4 hydrolysis
by: Ho, Xu En
Published: (2015)

Palladium(II) phosphine thiocarboxylates. Structures of cis-Pd(κS-SOCMe)2(dppf) [dppf=1,1′-bis(diphenylphosphino)ferrocene] and trans-Pd(κS-SOCMe)2(PPh3)2
by: Neo, Y.C., et al.
Published: (2014)

1,1′-Bis(diphenylphosphino)ferrocene complexes of gold(I). Polymeric [AuCl(μ-dppf)]n and dimeric [Au2(dppf-P,P′)2(μ-dppf)](NO3)2
by: Lai-Tee, P., et al.
Published: (2014)

Inter- and hetero-metallic assembly of palladium sulfide aggregates: Crystal and molecular structures of [InPd2Cl3(dppf) 2(μ3-S)2] · 3CH2Cl 2 and [Ag2Pd2(NO3) 2(dppf)2(μ3-S)2] · 2CH2Cl2
by: Li, G., et al.
Published: (2014)

PdCl[PPh 2CH 2CH 2CHCH 2CH 2PPh 2] as a precursor to homo-and hetero-metallic species directed by ESMS (electrospray ionisation mass spectrometry)
by: Neo, K.E., et al.
Published: (2014)

General formation of trigonal-prismatic [Ag6X 5(dppf)3]+ (X = Cl, Br, I) through an unusual ligand migration from NiX2(dppf) to AgOTf
by: Teo, P., et al.
Published: (2014)

Chemistry of 2-thienyl derivatives of arsenic and antimony: Synthesis and characterization; X-ray structure of [PdCl2{(C4H3S)3As}2]
by: Mahalakshmi, H., et al.
Published: (2014)

Destruksi sayuran pada analisis merkuri secara spektrometri serapan atom teknik penguapan dingin dengan pereduksi NaBH4
by: , SUSILANINGSIH, Endang, et al.
Published: (1992)

Facile ligand transformation from bridging thio to terminal chloromethanethiolato. Bridge opening of [Pt(μ-S)(dppf)]2 by dichloromethane to give Pt(SCH2Cl)2(dppf) [dppf Fe(C5H4PPh2)2]
by: Meisheng, Z., et al.
Published: (2014)

Substituted metal carbonyls. Part 21. [M(CO)5(dppf-P)] [M = Cr, Mo or W; Dppf = Fe(C5H4PPh2)2] as a metalloligand in heteropolymetallic aggregates of AuI, PdII and PtII. Crystal and molecular structures of [PtCl2{(μ-dppf)W(CO)5}2] and [Mo(CO)5(dppf-P)]
by: Phang, L.-T., et al.
Published: (2014)

Complexation of 1,1′-bis(diphenylphosphino)ferrocene dioxide (dppfO2) with 3d metals and revisit of its coordination to Pd(ii)
by: Zhang, W., et al.
Published: (2014)

Nitrato displacement in [Ag2(NO3)2(μ-dppf)2]. Molecular structure of a homoleptic dppf complex, [Ag2(μ-dppf)(dppf)2] (PF6)2 (dppf = 1,1′-bis(diphenylphosphino)ferrocene)
by: Neo, S.-P., et al.
Published: (2014)

Substituted metal carbonyls XII. Synthesis of Fe(CO)4(η1-dppf) (dppf = (Ph2PC5H4)2Fe) and its conversion into Fe2(CO)8(μ-dppf) and (CO)4Fe(μ-dppf)Mo(CO)5
by: Hor, T.S.A., et al.
Published: (2014)

Stereoelectronic properties of the sulfinyl-substituted phosphine ligands: synthesis and X-ray structure of the stable complex [PdCl2{Ph2PCH2S(O)Me}{MeOH}]
by: Quek, G.H., et al.
Published: (2014)

Catalytic dechlorination of chlorobenzenes: Effect of solvent on efficiency and selectivity
by: Lassová, L., et al.
Published: (2014)

Metal-metal cooperation via 1,1′-bis(diphenylphosphino)ferrocene (dppf). 1. Structurally distinctive silver(I) dppf complexes of nitrato and carboxylato ligands in variable coordination modes. Crystal structures of [Ag(NO3)(dppf)]2·2CHCl3, [Ag2(HCO2)2(dppf)3]·2CH 2Cl ...
by: Hor, T.S.A., et al.
Published: (2014)

Dalton communications. Synthesis and structural characterization of an Au-P linked chain polymer. The molecular structure of two pseudo-polymorphic forms of [{AuCl(μ-dppf)}n] [dppf = 1,1′-bis(diphenylphosphino)ferrocene]
by: Houlton, A., et al.
Published: (2014)

Pd(O2CCF2CF3-O)2(dppf) and PdAg(μ-O2CCF2CF3)2(O 2CCF2CF3-O)- (dppf)[dppf = 1,1′-bis(diphenylphosphino)ferrocene]: A stable Pd(II) phosphine carboxylate as a precursor to heterobimetallic carboxylates
by: Yew, C.N., et al.
Published: (2014)

Substituted metal carbonyls. Part XVII.1 1 For Part XVI see Ref. 1. Thermal decarbonylation and chelation of M(CO)5(η1-dppf) and Fe(CO)4(η1-dppf) [where M = Cr, Mo, W; dppf = (Ph2PC5H4)2Fe]
by: Hor, T.S.A., et al.
Published: (2014)

Cleavage of homometallic and formation of heterometallic M-M bonds. Serendipitous syntheses of bimetallic MnPd(μ-PPh2)-(CO)4(η2-P-P) (P-P = dppm, dppe, dppf) and polymetallic Mn2Pd2Ag(μ-Cl)(μ-PPh2)2 (μ-dppm)(CO)8
by: Liu, Y., et al.
Published: (2014)

Substituted metal carbonyls XV. Crystal and molecular structures of two isomorphous singly diphosphine-bridged complexes (OC)5M(μ-dppf)M(CO)5·CH2Cl2 (M = Cr, Mo; dppf = (Ph2PC5H4)2Fe)
by: Hor, T.S.A., et al.
Published: (2014)

Isolation and structural characterization of some stable Pd(II) carboxylate complexes supported by 1,1′-bis(diphenylphosphino) ferrocene (dppf)
by: Neo, Y.C., et al.
Published: (2014)

Reductive Dehalogenation of Chlorophenols by Anaerobic Microbial Consortia
by: CHUAH CHONG JOON
Published: (2010)

Reductive Dehalogenation of Cholorinated Hydrocarbons by Established Cocultures
by: WANG ZIHAN
Published: (2015)

Trace analysis of ten chlorinated benzenes in water by headspace solid-phase microextraction
by: He, Y., et al.
Published: (2014)

Phylogenetically Distinct Bacteria Involve Extensive Dechlorination of Aroclor 1260 in Sediment-Free Cultures
by: Wang, S., et al.
Published: (2014)

Phylogenetically Distinct Bacteria Involve Extensive Dechlorination of Aroclor 1260 in Sediment-Free Cultures
by: Wang, S., et al.
Published: (2014)

Co-ordination and catalytic chemistry of 1,1′-bis(diphenylphosphino)-ruthenocene (dppr). Synthesis of [MCl2(dppr)] (M = Ni, Pd or Pt) and molecular structures of dppr and [PtCl2(dppr)]·0.5CH2Cl2
by: Li, S., et al.
Published: (2014)

Synthesis of M0(η2-dppf)2 (M Pd, Pt; dppf Fe(C5H4PPh2)2) and their reactions with Fe3(μ3-S)2(CO)9 and elemental sulfur
by: Fang, Z.-G., et al.
Published: (2014)

Synthesis of Ag/Bi <inf>2</inf> MoO <inf>6</inf> Nanocomposites Using NaBH <inf>4</inf> as Reducing Agent for Enhanced Visible-Light-Driven Photocatalysis of Rhodamine B
by: Anukorn Phuruangrat, et al.
Published: (2019)

Solution characterization, conformation analysis, and dynamics of the ligand 1,1′-bis(diphenylphosphino)ferrocene (dppf) in Re2(μ-OMe)2(μ-dppf)(CO)6
by: Lam, S.-L., et al.
Published: (2014)

[Pt2(dppf)2(μ-S)2] as a heterometallic ligand. Simple assembly of an electroactive interpolymetallic complex [Pt2Tl(dppf)2(μ-S)2]X (X = NO3, PF6) (dppf = 1,1′-bis(diphenylphosphino)ferrocene)
by: Zhou, M., et al.
Published: (2014)