Facile ligand transformation from bridging thio to terminal chloromethanethiolato. Bridge opening of [Pt(μ-S)(dppf)]2 by dichloromethane to give Pt(SCH2Cl)2(dppf) [dppf Fe(C5H4PPh2)2]

Facile ligand transformation from bridging thio to terminal chloromethanethiolato. Bridge opening of [Pt(μ-S)(dppf)]2 by dichloromethane to give Pt(SCH2Cl)2(dppf) [dppf Fe(C5H4PPh2)2]

Journal of Organometallic Chemistry

Saved in:

Bibliographic Details
Main Authors:	Meisheng, Z., Choon, F.L., Mok, K.F., Pak-Hing, L., Hor, T.S.A.
Other Authors:	CHEMISTRY
Format:	Article
Published:	2014
Subjects:	Diphosphine Ferrocene Phosphine Platinum Sulfide Thiolate
Online Access:	http://scholarbank.nus.edu.sg/handle/10635/93794
Tags:	Add Tag No Tags, Be the first to tag this record!
Institution:	National University of Singapore

Similar Items

1,1′-Bis(diphenylphosphino)ferrocene complexes of gold(I). Polymeric [AuCl(μ-dppf)]n and dimeric [Au2(dppf-P,P′)2(μ-dppf)](NO3)2
by: Lai-Tee, P., et al.
Published: (2014)

Synthesis of M0(η2-dppf)2 (M Pd, Pt; dppf Fe(C5H4PPh2)2) and their reactions with Fe3(μ3-S)2(CO)9 and elemental sulfur
by: Fang, Z.-G., et al.
Published: (2014)

Palladium(II) phosphine thiocarboxylates. Structures of cis-Pd(κS-SOCMe)2(dppf) [dppf=1,1′-bis(diphenylphosphino)ferrocene] and trans-Pd(κS-SOCMe)2(PPh3)2
by: Neo, Y.C., et al.
Published: (2014)

Nitrato displacement in [Ag2(NO3)2(μ-dppf)2]. Molecular structure of a homoleptic dppf complex, [Ag2(μ-dppf)(dppf)2] (PF6)2 (dppf = 1,1′-bis(diphenylphosphino)ferrocene)
by: Neo, S.-P., et al.
Published: (2014)

Clusters and Aggregates of 1, 1′-Bis(diphenylphosphino)ferrocene (dppf)
by: Audi Fong, S.-W., et al.
Published: (2014)

Clusters and Aggregates of 1, 1′-Bis(diphenylphosphino)ferrocene (dppf)
by: Audi Fong, S.-W., et al.
Published: (2014)

General synthesis of ferrocenylphosphine-bridged digold carboxylato complexes: Crystal and molecular structure of Au2(η1-CF3CO2) 2(μ-dppf) · C6H14 (dppf = Fe(C5H4PPh2)2)
by: Low, P.M.N., et al.
Published: (2014)

Inter- and hetero-metallic assembly of palladium sulfide aggregates: Crystal and molecular structures of [InPd2Cl3(dppf) 2(μ3-S)2] · 3CH2Cl 2 and [Ag2Pd2(NO3) 2(dppf)2(μ3-S)2] · 2CH2Cl2
by: Li, G., et al.
Published: (2014)

Coordination polymers and supramolecular structures in Ag(I)triflate-dppf systems (dppf=1,1′-bis(diphenylphosphino) ferrocene)
by: Lu, X.L., et al.
Published: (2014)

[Pt2(dppf)2(μ-S)2] as a heterometallic ligand. Simple assembly of an electroactive interpolymetallic complex [Pt2Tl(dppf)2(μ-S)2]X (X = NO3, PF6) (dppf = 1,1′-bis(diphenylphosphino)ferrocene)
by: Zhou, M., et al.
Published: (2014)

Methylation of [Pt2(μ-SR)(μ-S)(PPh3) 4]: En route to mixed-thiolato bridged complexes
by: Chong, S.H., et al.
Published: (2014)

Reactivities and template syntheses of / on the {Pt2S2} core towards organic electrophiles
by: CHONG SIEW HUAY
Published: (2011)

Heterometallic multinuclear Pt-M (M=Au, Ag) structural assemblies from dinuclear [Pt2(P-P)2(μ-S)2] (P-P = 2PPh3, dppf)
by: Li, Z., et al.
Published: (2014)

Chloride substitution of [CpRu(dppf)Cl] with sulfur-containing ligands
by: Lu, X.L., et al.
Published: (2014)

Comparative reactivity studies of dppf-containing CpRuII and (C6Me6)RuII complexes towards different donor ligands (dppf=1,1′-bis(diphenylphosphino)ferrocene)
by: Lu, X.L., et al.
Published: (2014)

Isolation and structural characterization of some stable Pd(II) carboxylate complexes supported by 1,1′-bis(diphenylphosphino) ferrocene (dppf)
by: Neo, Y.C., et al.
Published: (2014)

Metal-metal cooperation via 1,1′-bis(diphenylphosphino)ferrocene (dppf). 1. Structurally distinctive silver(I) dppf complexes of nitrato and carboxylato ligands in variable coordination modes. Crystal structures of [Ag(NO3)(dppf)]2·2CHCl3, [Ag2(HCO2)2(dppf)3]·2CH 2Cl ...
by: Hor, T.S.A., et al.
Published: (2014)

Substituted metal carbonyls XII. Synthesis of Fe(CO)4(η1-dppf) (dppf = (Ph2PC5H4)2Fe) and its conversion into Fe2(CO)8(μ-dppf) and (CO)4Fe(μ-dppf)Mo(CO)5
by: Hor, T.S.A., et al.
Published: (2014)

Ferrocenyl phosphine mobility, positional isomerism and NMR fluxionality in triangular palladium sulfide aggregates. Crystal and molecular structures of [Pd3Cl2(η2-dppf)(μ-dppf)(μ 3-S)2] and [Pd3Cl(η2-dppf)2(PPh3)(μ 3-S)2]X [X = Cl or NO3, dppf = ...
by: Yeo, J.S.L., et al.
Published: (2014)

Substituted metal carbonyls. Part 21. [M(CO)5(dppf-P)] [M = Cr, Mo or W; Dppf = Fe(C5H4PPh2)2] as a metalloligand in heteropolymetallic aggregates of AuI, PdII and PtII. Crystal and molecular structures of [PtCl2{(μ-dppf)W(CO)5}2] and [Mo(CO)5(dppf-P)]
by: Phang, L.-T., et al.
Published: (2014)

Stabilization of a Y-shaped Cu1 coordination in [CuPt2(PPh3)5(μ3-S) 2]PF6 by Pt2(PPh3)4(μ-S)2 and its expansion to a pentanuclear aggregate [Cu{Pt2(PPh3)4(μ3-S) 2}2]PF6.
by: Liu, H., et al.
Published: (2014)

Solution characterization, conformation analysis, and dynamics of the ligand 1,1′-bis(diphenylphosphino)ferrocene (dppf) in Re2(μ-OMe)2(μ-dppf)(CO)6
by: Lam, S.-L., et al.
Published: (2014)

Dinuclear platinum(II) sulfide-thiolate complexes [Pt2(μ-S) (μ-SR)(PPh3)4]+ containing fluorinated substituents and the identification of a S⋯C6F5 π interaction in the crystal structure of [Pt2(μ-S)(μ- SCH2C6F5)(PPh3)4]BPh 4·2C
by: Henderson, W., et al.
Published: (2014)

Reactions of the complexes [Re2(CO)9(η 1-P-P)] (P-P = Ph2P(CH2)nPPh 2, n = 1-6) with Me3NO: Formation of close-bridged complexes [Re2(CO)8(μ-P-P)] and phosphine oxide complexes [Re2(CO)9{P-P(O)}]
by: Fan, W., et al.
Published: (2014)

Synthesis, X-ray crystal structures and electrochemistry of (indenyl)-ruthenium complexes containing dppf and heterocyclic thiolato/thione ligands
by: Sin, Y.N., et al.
Published: (2014)

The arylation of [Pt2(μ-S)2(PPh3)4]
by: Deadman, B.J., et al.
Published: (2014)

(Indenyl)ruthenium complexes containing 1,1′-bis(diphenylphosphanyl)- ferrocene (dppf) and thiolato ligands: Synthesis, X-ray structure analysis, electrochemistry and magnetic studies
by: Sin, Y.N., et al.
Published: (2014)

Structural dynamics and ligand mobility in carboxylate and dithiocarbamate complexes of Ru(II) containing 1,1′-bis (diphenylphosphino)ferrocene (dppf)
by: Lu, X.L., et al.
Published: (2014)

Heteropolymetallic aggregates from [Pd2(dppf)2(μ-S)2]. Bonding and structural analysis of [Ag2Pd2Cl2(dppf)2(μ 3-S)2]·4CH2Cl2 [dppf = Fe(C5H4PPh2)2] - A flat {Pd2S2} core with two AgCl 'tails'
by: Li, G., et al.
Published: (2014)

Dithiolate and diselenolate complexes [Pt2(μ-ECH2CH{double bond, long}CHCH2E)(PPh3)4]2+ (E = S, Se): Synthesis, characterisation and mass spectrometric formation of the dichalcogenide species [Pt2(μ-E2)(PPh3)4]2+
by: Devoy, S.M., et al.
Published: (2014)

Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt2(μ-S)2(PPh3) 4]
by: Ujam, O.T., et al.
Published: (2014)

Pd(O2CCF2CF3-O)2(dppf) and PdAg(μ-O2CCF2CF3)2(O 2CCF2CF3-O)- (dppf)[dppf = 1,1′-bis(diphenylphosphino)ferrocene]: A stable Pd(II) phosphine carboxylate as a precursor to heterobimetallic carboxylates
by: Yew, C.N., et al.
Published: (2014)

Substituted metal carbonyls XV. Crystal and molecular structures of two isomorphous singly diphosphine-bridged complexes (OC)5M(μ-dppf)M(CO)5·CH2Cl2 (M = Cr, Mo; dppf = (Ph2PC5H4)2Fe)
by: Hor, T.S.A., et al.
Published: (2014)

Substituted metal carbonylsXVIII. rhenium 1,1′-bis(diphenylphosphino)ferrocene (DPPF) complexes derived from [Re2(CO)9]. Crystal structures of two isomorphous pentametallic [M2(CO)9]2(μ-dppf) (M Mn, Re) and trimetallic Re2(CO)9(dppfO) complexes
by: Hor, T.S.A., et al.
Published: (2014)

X-Ray photoelectron spectroscopic characterization of [{Pt(PPh3)2(μ3-S)}2PtCl 2], [{Pt2(PPh3)4(μ3-S) 2Cu}2(μ-dppf)][PF6]2 [dppf = Fe (C5H4PPh2)2] and other heterometallic aggregates derived from...
by: Aw, B.H., et al.
Published: (2014)

Complete debromination of polybrominated benzenes at room temperature catalyzed by palladium metallocenyl diphosphine complexes
by: Wei, B., et al.
Published: (2014)

Substituted metal carbonyls XIII. Fe(CO)4(η1-dppf) [where dppf = (Ph2PC5H4)2Fe]: a convenient building block for heterometallic complexes
by: Andy Hor, T.S., et al.
Published: (2014)

Electronic interactions in dinuclear platinum and palladium ethynylferrocene and ferrocenylvinylidene complexes
by: Yip, J.H.K., et al.
Published: (2014)

Synthesis of compounds with an organic bridge over the {Pt2(mu-S)2} moiety
by: WANG JIANMING
Published: (2011)

Promotion of tetrahedral copper(I) dimers by chelation of 1,1′-bis(diphenylphosphino)ferrocene (dppf). Crystal structures of [{Cu(μ-X)(dppf-P,P′)}2](X = O2CH, I or NO3)
by: Neo, S.P., et al.
Published: (2014)