Synthesis of M0(η2-dppf)2 (M Pd, Pt; dppf Fe(C5H4PPh2)2) and their reactions with Fe3(μ3-S)2(CO)9 and elemental sulfur

Synthesis of M0(η2-dppf)2 (M Pd, Pt; dppf Fe(C5H4PPh2)2) and their reactions with Fe3(μ3-S)2(CO)9 and elemental sulfur

Journal of Organometallic Chemistry

Saved in:

Bibliographic Details
Main Authors:	Fang, Z.-G., Low, P.M.N., Ng, S.-C., Andy Hor, T.S.
Other Authors:	CHEMISTRY
Format:	Article
Published:	2014
Subjects:	Cluster Diphosphine Ferrocenyl phosphine Palladium Platinum Sulfur
Online Access:	http://scholarbank.nus.edu.sg/handle/10635/95126
Tags:	Add Tag No Tags, Be the first to tag this record!
Institution:	National University of Singapore

Similar Items

Facile ligand transformation from bridging thio to terminal chloromethanethiolato. Bridge opening of [Pt(μ-S)(dppf)]2 by dichloromethane to give Pt(SCH2Cl)2(dppf) [dppf Fe(C5H4PPh2)2]
by: Meisheng, Z., et al.
Published: (2014)

Palladium(II) phosphine thiocarboxylates. Structures of cis-Pd(κS-SOCMe)2(dppf) [dppf=1,1′-bis(diphenylphosphino)ferrocene] and trans-Pd(κS-SOCMe)2(PPh3)2
by: Neo, Y.C., et al.
Published: (2014)

Inter- and hetero-metallic assembly of palladium sulfide aggregates: Crystal and molecular structures of [InPd2Cl3(dppf) 2(μ3-S)2] · 3CH2Cl 2 and [Ag2Pd2(NO3) 2(dppf)2(μ3-S)2] · 2CH2Cl2
by: Li, G., et al.
Published: (2014)

1,1′-Bis(diphenylphosphino)ferrocene complexes of gold(I). Polymeric [AuCl(μ-dppf)]n and dimeric [Au2(dppf-P,P′)2(μ-dppf)](NO3)2
by: Lai-Tee, P., et al.
Published: (2014)

Isolation and structural characterization of some stable Pd(II) carboxylate complexes supported by 1,1′-bis(diphenylphosphino) ferrocene (dppf)
by: Neo, Y.C., et al.
Published: (2014)

Clusters and Aggregates of 1, 1′-Bis(diphenylphosphino)ferrocene (dppf)
by: Audi Fong, S.-W., et al.
Published: (2014)

Clusters and Aggregates of 1, 1′-Bis(diphenylphosphino)ferrocene (dppf)
by: Audi Fong, S.-W., et al.
Published: (2014)

General synthesis of ferrocenylphosphine-bridged digold carboxylato complexes: Crystal and molecular structure of Au2(η1-CF3CO2) 2(μ-dppf) · C6H14 (dppf = Fe(C5H4PPh2)2)
by: Low, P.M.N., et al.
Published: (2014)

Methylation of [Pt2(μ-SR)(μ-S)(PPh3) 4]: En route to mixed-thiolato bridged complexes
by: Chong, S.H., et al.
Published: (2014)

Ferrocenyl iminophosphine ligands in Pd-catalysed Suzuki couplings
by: Teo, S., et al.
Published: (2014)

Complete debromination of polybrominated benzenes at room temperature catalyzed by palladium metallocenyl diphosphine complexes
by: Wei, B., et al.
Published: (2014)

Stabilization of a Y-shaped Cu1 coordination in [CuPt2(PPh3)5(μ3-S) 2]PF6 by Pt2(PPh3)4(μ-S)2 and its expansion to a pentanuclear aggregate [Cu{Pt2(PPh3)4(μ3-S) 2}2]PF6.
by: Liu, H., et al.
Published: (2014)

Heterometallic multinuclear Pt-M (M=Au, Ag) structural assemblies from dinuclear [Pt2(P-P)2(μ-S)2] (P-P = 2PPh3, dppf)
by: Li, Z., et al.
Published: (2014)

Ferrocenyl phosphine mobility, positional isomerism and NMR fluxionality in triangular palladium sulfide aggregates. Crystal and molecular structures of [Pd3Cl2(η2-dppf)(μ-dppf)(μ 3-S)2] and [Pd3Cl(η2-dppf)2(PPh3)(μ 3-S)2]X [X = Cl or NO3, dppf = ...
by: Yeo, J.S.L., et al.
Published: (2014)

Substituted metal carbonyls XII. Synthesis of Fe(CO)4(η1-dppf) (dppf = (Ph2PC5H4)2Fe) and its conversion into Fe2(CO)8(μ-dppf) and (CO)4Fe(μ-dppf)Mo(CO)5
by: Hor, T.S.A., et al.
Published: (2014)

Substituted metal carbonyls. Part XVII.1 1 For Part XVI see Ref. 1. Thermal decarbonylation and chelation of M(CO)5(η1-dppf) and Fe(CO)4(η1-dppf) [where M = Cr, Mo, W; dppf = (Ph2PC5H4)2Fe]
by: Hor, T.S.A., et al.
Published: (2014)

Reactions of the complexes [Re2(CO)9(η 1-P-P)] (P-P = Ph2P(CH2)nPPh 2, n = 1-6) with Me3NO: Formation of close-bridged complexes [Re2(CO)8(μ-P-P)] and phosphine oxide complexes [Re2(CO)9{P-P(O)}]
by: Fan, W., et al.
Published: (2014)

Immobilization of [Pt 2(μ-S) 2(PPh 3)4] on polymeric supports by sulfide alkylation and phosphine exchange reactions
by: Ujam, O.T., et al.
Published: (2014)

Nitrato displacement in [Ag2(NO3)2(μ-dppf)2]. Molecular structure of a homoleptic dppf complex, [Ag2(μ-dppf)(dppf)2] (PF6)2 (dppf = 1,1′-bis(diphenylphosphino)ferrocene)
by: Neo, S.-P., et al.
Published: (2014)

X-Ray photoelectron spectroscopic characterization of [{Pt(PPh3)2(μ3-S)}2PtCl 2], [{Pt2(PPh3)4(μ3-S) 2Cu}2(μ-dppf)][PF6]2 [dppf = Fe (C5H4PPh2)2] and other heterometallic aggregates derived from...
by: Aw, B.H., et al.
Published: (2014)

[Pt2(PPh3)4(μ-S)2] as a metalloligand toward main-group Lewis acids: Theoretical study of intermetallic complexes with T1(I), Pb(II), In(III) and Ga(III)
by: Tan, A.L., et al.
Published: (2014)

Substituted metal carbonyls XIII. Fe(CO)4(η1-dppf) [where dppf = (Ph2PC5H4)2Fe]: a convenient building block for heterometallic complexes
by: Andy Hor, T.S., et al.
Published: (2014)

Heteropolymetallic aggregates from [Pd2(dppf)2(μ-S)2]. Bonding and structural analysis of [Ag2Pd2Cl2(dppf)2(μ 3-S)2]·4CH2Cl2 [dppf = Fe(C5H4PPh2)2] - A flat {Pd2S2} core with two AgCl 'tails'
by: Li, G., et al.
Published: (2014)

An electrospray mass spectrometry-directed survey of the coordination chemistry of the metalloligand [Pt2(μ-S)2(PPh 3)4] with platinum(II) and palladium(II) chloride substrates: Influence of metal-ligand lability on product type
by: Fong, S.-W.A., et al.
Published: (2014)

Substituted metal carbonyls. Part 21. [M(CO)5(dppf-P)] [M = Cr, Mo or W; Dppf = Fe(C5H4PPh2)2] as a metalloligand in heteropolymetallic aggregates of AuI, PdII and PtII. Crystal and molecular structures of [PtCl2{(μ-dppf)W(CO)5}2] and [Mo(CO)5(dppf-P)]
by: Phang, L.-T., et al.
Published: (2014)

Synthesis and characterisation of adducts of [Pt2(μ-S) 2(PPh3)4] with organo-palladium and platinum-hydride substrates
by: White, B.C., et al.
Published: (2014)

Chloride substitution of [CpRu(dppf)Cl] with sulfur-containing ligands
by: Lu, X.L., et al.
Published: (2014)

Substituted metal carbonyls XV. Crystal and molecular structures of two isomorphous singly diphosphine-bridged complexes (OC)5M(μ-dppf)M(CO)5·CH2Cl2 (M = Cr, Mo; dppf = (Ph2PC5H4)2Fe)
by: Hor, T.S.A., et al.
Published: (2014)

Room-temperature hydrodebromination of 4,4'-dibromobiphenyl catalyzed by 1,1'-bis(diphenylphosphino) ferrocene complexes of palladium
by: Wei, B., et al.
Published: (2014)

Syntheses and structures of palladium(II) and platinum(II) complexes with tridentate (Ph2PCH2CH2CH2)2S and its arsenic analogue
by: Cheng, C.R., et al.
Published: (2014)

Cleavage of homometallic and formation of heterometallic M-M bonds. Serendipitous syntheses of bimetallic MnPd(μ-PPh2)-(CO)4(η2-P-P) (P-P = dppm, dppe, dppf) and polymetallic Mn2Pd2Ag(μ-Cl)(μ-PPh2)2 (μ-dppm)(CO)8
by: Liu, Y., et al.
Published: (2014)

{M3S2} heterometallic aggregates derived from Pt2(PPh3)4(μ-S)2: Structural analysis of [MPt2X(PPh3)5(μ3-S) 2]+ (M=Pd and Pt, X=Cl; M=Rh and Ir, X=CO) by X-ray single-crystal crystallography
by: Li, Z., et al.
Published: (2014)

Tuning the sulfur-heterometal interaction in organolead(IV) complexes of [Pt2(μ-S)2(PPh3)4]
by: Pham, K., et al.
Published: (2014)

[Pt2(dppf)2(μ-S)2] as a heterometallic ligand. Simple assembly of an electroactive interpolymetallic complex [Pt2Tl(dppf)2(μ-S)2]X (X = NO3, PF6) (dppf = 1,1′-bis(diphenylphosphino)ferrocene)
by: Zhou, M., et al.
Published: (2014)

Facile reductive excision of sulfur from a {Pt2S2} core in [Pt2(PPh3)4(μ-S)2] to a {Pt2S} triangle by carbon monoxide
by: Chin, C.H., et al.
Published: (2014)

Metal-metal cooperation via 1,1′-bis(diphenylphosphino)ferrocene (dppf). 1. Structurally distinctive silver(I) dppf complexes of nitrato and carboxylato ligands in variable coordination modes. Crystal structures of [Ag(NO3)(dppf)]2·2CHCl3, [Ag2(HCO2)2(dppf)3]·2CH 2Cl ...
by: Hor, T.S.A., et al.
Published: (2014)

Thallium(III) complexes of the metalloligands [Pt2(μ-S)2(PPh3)4] and [Pt2(μ-Se)2(PPh3)4]
by: Rose, S.L., et al.
Published: (2014)

Reactions of [Pt2(μ-S)2(PPh3)4] with Group 6 and 7 metal carbonyls; Crystal structure of the apparently unsaturated heterometallic complex [Pt2Re(μ3-S)2(PPh3) 4(CO)3]+
by: Liu, H., et al.
Published: (2014)

Substituted metal carbonylsXVIII. rhenium 1,1′-bis(diphenylphosphino)ferrocene (DPPF) complexes derived from [Re2(CO)9]. Crystal structures of two isomorphous pentametallic [M2(CO)9]2(μ-dppf) (M Mn, Re) and trimetallic Re2(CO)9(dppfO) complexes
by: Hor, T.S.A., et al.
Published: (2014)

The arylation of [Pt2(μ-S)2(PPh3)4]
by: Deadman, B.J., et al.
Published: (2014)