Tuning the sulfur-heterometal interaction in organolead(IV) complexes of [Pt2(μ-S)2(PPh3)4]

Tuning the sulfur-heterometal interaction in organolead(IV) complexes of [Pt2(μ-S)2(PPh3)4]

10.1016/j.jorganchem.2007.07.010

Saved in:

Bibliographic Details
Main Authors:	Pham, K., Henderson, W., Nicholson, B.K., Hor, T.S.A.
Other Authors:	CHEMISTRY
Format:	Article
Published:	2014
Subjects:	Crystal structures Electrospray mass spectrometry Lead complexes Platinum complexes Sulfide ligands
Online Access:	http://scholarbank.nus.edu.sg/handle/10635/95361
Tags:	Add Tag No Tags, Be the first to tag this record!
Institution:	National University of Singapore

Similar Items

Thallium(III) complexes of the metalloligands [Pt2(μ-S)2(PPh3)4] and [Pt2(μ-Se)2(PPh3)4]
by: Rose, S.L., et al.
Published: (2014)

Using electrospray ionisation mass spectrometry as a synthesis-targeting technique - An update on the chemistry of the platinum chalcogenide dimers [Pt2(μ2-E)2(PPh3)4] (E = S, Se)
by: Henderson, W., et al.
Published: (2014)

The arylation of [Pt2(μ-S)2(PPh3)4]
by: Deadman, B.J., et al.
Published: (2014)

Moderating the nucleophilicity of the sulfide ligands in the dinuclear {Pt2S2} metalloligand system using triphenylarsine
by: Jeram, S., et al.
Published: (2014)

Dithiolate and diselenolate complexes [Pt2(μ-ECH2CH{double bond, long}CHCH2E)(PPh3)4]2+ (E = S, Se): Synthesis, characterisation and mass spectrometric formation of the dichalcogenide species [Pt2(μ-E2)(PPh3)4]2+
by: Devoy, S.M., et al.
Published: (2014)

Coordination chemistry of the [Pt2(μ-S)2 (PPh3)4] metalloligand with π-hydrocarbon derivatives of d6 ruthenium(II), osmium(II), rhodium(III) and iridium(III)
by: Audi Fong, S.-W., et al.
Published: (2014)

Synthesis and structural characterisation of the lead-platinum sulfido aggregates [Pt2(μ-S)2(PPh3)4PbX2] (X = Br, I); promotion of rare tetrahedral geometry for lead(II)
by: Henderson, W., et al.
Published: (2014)

Coordination chemistry of the metalloligand [Pt2(μ-S) 2(PPh3)4] with nickel(II) complexes - An electrospray mass spectrometry directed synthetic study
by: Fong, S.-W.A., et al.
Published: (2014)

Dinuclear sulfide-thiolate complexes [Pt2(μ-S)(μ-SR)(PPh3)4]+ as cationic metalloligands
by: Henderson, W., et al.
Published: (2014)

'Synthetic prospecting' using an electrospray ionisation mass spectrometry directed survey of the alkylation and arylation chemistry of [Pt2(μ-S)2(PPh3)4]
by: Henderson, W., et al.
Published: (2014)

Further studies on the chemistry of molybdenyl adducts of [Pt 2(μ-S)2(PPh3)4]: Hydrolysis, condensation and ligand exchange processes
by: Henderson, W., et al.
Published: (2014)

Heterobimetallic platinum-bismuth aggregates derived from [Pt 2(μ-S)2(PPh3)4]
by: Henderson, W., et al.
Published: (2014)

Influence of chain length on mono- versus di-alkylation in the reactivity of [Pt2(μ-S)2(PPh3)4] towards α,ω-dihalo-n-alkanes; a synthetic route to platinum(II) ω-haloalkylthiolate complexes
by: Devoy, S.M., et al.
Published: (2014)

Synthesis and characterisation of adducts of [Pt2(μ-S) 2(PPh3)4] with organo-palladium and platinum-hydride substrates
by: White, B.C., et al.
Published: (2014)

Synthesis and characterisation of [Pt2(μ-S)(μ-I)(PPh3)4]+ - A cationic iodo analogue of the metalloligand [Pt2(μ-S)2(PPh3)4]
by: Audi Fong, S.-W., et al.
Published: (2014)

Hydrogen bonding in crystalline alcohol solvates of the platinum(II) sulfido complex [Pt2(μ-S)2(PPh3) 4]
by: Henderson, W., et al.
Published: (2014)

Spanning [Pt2(μ-S)2(PPh3)4] metalloligands with 1,4-dimercurated durene
by: Cameron, N.E., et al.
Published: (2014)

Further studies on the dialkylation chemistry of [Pt2(μ-S) 2(PPh3)4] with activated alkyl halides RC(O)CH2X (X = Cl, Br)
by: Ujam, O.T., et al.
Published: (2014)

Sulfide-bridged aggregates from the metalloligand [Pt2(μ-S) 2(PPh3)4] and β-diketonate complexes of cobalt(II) and zinc(II)
by: Bridson, J.H., et al.
Published: (2014)

An electrospray mass spectrometry-directed survey of the coordination chemistry of the metalloligand [Pt2(μ-S)2(PPh 3)4] with platinum(II) and palladium(II) chloride substrates: Influence of metal-ligand lability on product type
by: Fong, S.-W.A., et al.
Published: (2014)

Synthesis and characterization of new trimetallic complexes with {Pt 2Au(μ-S) 2} n+ (n = 2, 3) cores containing C, N and N, N donor ligands
by: White, B.C., et al.
Published: (2014)

Immobilization of [Pt 2(μ-S) 2(PPh 3)4] on polymeric supports by sulfide alkylation and phosphine exchange reactions
by: Ujam, O.T., et al.
Published: (2014)

Dinuclear platinum(II) sulfide-thiolate complexes [Pt2(μ-S) (μ-SR)(PPh3)4]+ containing fluorinated substituents and the identification of a S⋯C6F5 π interaction in the crystal structure of [Pt2(μ-S)(μ- SCH2C6F5)(PPh3)4]BPh 4·2C
by: Henderson, W., et al.
Published: (2014)

Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt2(μ-S)2(PPh3) 4]
by: Ujam, O.T., et al.
Published: (2014)

Pressure-assisted hetero- and homodialkylation of sulfide in [Pt 2(μ-S)2(dppp)2]: One-pot conversion of {Pt2(μ-S)2} into Pt2(SR)2J and {Pt2(SR)(SR′)}
by: Chong, S.H., et al.
Published: (2014)

Facile reductive excision of sulfur from a {Pt2S2} core in [Pt2(PPh3)4(μ-S)2] to a {Pt2S} triangle by carbon monoxide
by: Chin, C.H., et al.
Published: (2014)

Methylation of [Pt2(μ-SR)(μ-S)(PPh3) 4]: En route to mixed-thiolato bridged complexes
by: Chong, S.H., et al.
Published: (2014)

Reactions of [Pt2(μ-S)2(PPh3)4] with Group 6 and 7 metal carbonyls; Crystal structure of the apparently unsaturated heterometallic complex [Pt2Re(μ3-S)2(PPh3) 4(CO)3]+
by: Liu, H., et al.
Published: (2014)

Electrospray mass spectrometric investigation of the reactivity of the sulfide centers in [Pt2(μ-S)2(PPh3) 4] towards organic dihalides and the catalytic potential of this complex in the syntheses of organosulfur materials
by: Chong, S.H., et al.
Published: (2014)

Stabilization of a Y-shaped Cu1 coordination in [CuPt2(PPh3)5(μ3-S) 2]PF6 by Pt2(PPh3)4(μ-S)2 and its expansion to a pentanuclear aggregate [Cu{Pt2(PPh3)4(μ3-S) 2}2]PF6.
by: Liu, H., et al.
Published: (2014)

Facile ligand transformation from bridging thio to terminal chloromethanethiolato. Bridge opening of [Pt(μ-S)(dppf)]2 by dichloromethane to give Pt(SCH2Cl)2(dppf) [dppf Fe(C5H4PPh2)2]
by: Meisheng, Z., et al.
Published: (2014)

[Pt2(PPh3)4(μ-S)2] as a metalloligand toward main-group Lewis acids. Crystal structures and bonding analysis of two low-coordinate BiCl3 adducts.
by: Zhou, M.S., et al.
Published: (2014)

Synthesis of diimineplatinum(II) complexes containing the 1,2-dicarba-closo-dodecaborane(12)-1-thiolato ligand
by: Todd, J.A., et al.
Published: (2014)

{M3S2} heterometallic aggregates derived from Pt2(PPh3)4(μ-S)2: Structural analysis of [MPt2X(PPh3)5(μ3-S) 2]+ (M=Pd and Pt, X=Cl; M=Rh and Ir, X=CO) by X-ray single-crystal crystallography
by: Li, Z., et al.
Published: (2014)

Open platinum aggregate frameworks with overhead dithiolate bridges
by: Siew, H.C., et al.
Published: (2014)

Heterometallic multinuclear Pt-M (M=Au, Ag) structural assemblies from dinuclear [Pt2(P-P)2(μ-S)2] (P-P = 2PPh3, dppf)
by: Li, Z., et al.
Published: (2014)

Complexes of platinum(II) or palladium(II) with 1,10-phenanthroline and amino acids
by: Jin, V.X., et al.
Published: (2014)

Combinative use of high-pressure, metal-templating and sulfur- nucleophilicity towards dithiacyclophane synthesis and its complex intermediates
by: Chong, S.H., et al.
Published: (2014)

Layered crystalline and amorphous platinum disulfide (PtS₂) : contrasting electrochemistry
by: Wang, Yong, et al.
Published: (2021)

Ruthenocenyl ruthenium bimetallic complexes: Electrospray mass spectrometric study of [RuX(η5-C5H5)(η2-dppr)] n+ (dppr=1,1′-bis(diphenylphosphino)ruthenocene) (X=Cl, n=0; X=CO, CH3CN, C=CHPh, n=1) and the X-ray crystal and molecular structure of [Ru(η5-C5H5)(CO)(η 2-dppr)]PF6
by: Po Yeo, S., et al.
Published: (2014)