Photocatalytic degradation of methyl orange by CeO2 and Fe-doped CeO2 films under visible light irradiation

Undoped CeO2 and 0.50-5.00 mol% Fe-doped CeO2 nanoparticles were prepared by a homogeneous precipitation combined with homogeneous/impreganation method, and applied as photocatalyst films prepared by a doctor blade technique. The superior photocatalytic performances of the Fe-doped CeO2 films, compa...

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Bibliographic Details
Main Authors: Channei D., Inceesungvorn B., Wetchakun N., Ukritnukun S., Nattestad A., Chen J., Phanichphant S.
Format: Article
Language:English
Published: Nature Publishing Group 2014
Online Access:http://www.scopus.com/inward/record.url?eid=2-s2.0-84906817999&partnerID=40&md5=85b4be55cdd1fe9a1dda187e0be4ec67
http://cmuir.cmu.ac.th/handle/6653943832/37639
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Institution: Chiang Mai University
Language: English
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Summary:Undoped CeO2 and 0.50-5.00 mol% Fe-doped CeO2 nanoparticles were prepared by a homogeneous precipitation combined with homogeneous/impreganation method, and applied as photocatalyst films prepared by a doctor blade technique. The superior photocatalytic performances of the Fe-doped CeO2 films, compared with undoped CeO2 films, was ascribed mainly to a decrease in band gap energy and an increase in specific surface area of the material. The presence of Fe31 as found from XPS analysis, may act as electron acceptor and/or hole donor, facilitating longer lived charge carrier separation in Fe-doped CeO2 films as confirmed by photoluminescence spectroscopy. The 1.50 mol% Fe-doped CeO2 film was found to be the optimal iron doping concentration for MO degradation in this study.