Improvement of ferroelectric properties of PZT ceramics by SBT addition

(1-x)PZT-xSBT ceramics were prepared by a solid-state mixed oxide method. Phase characteristics of (1-x)PZT-xSBT ceramics showed a PZT phase and new phase in the compositions with 0.1 ≤ x ≤ 0.3, while a mainly new phase was observed in the compositionwith x=0.5. The tetragonality (c/a) of PZT phase...

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Bibliographic Details
Main Authors: Namsar,O., Watcharapasorn,A., Hoffman,M.J., Glaum,J., Jiansirisomboon,S.
Format: Article
Published: Taylor and Francis Ltd. 2015
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Online Access:http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84901358006&origin=inward
http://cmuir.cmu.ac.th/handle/6653943832/38736
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Institution: Chiang Mai University
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Summary:(1-x)PZT-xSBT ceramics were prepared by a solid-state mixed oxide method. Phase characteristics of (1-x)PZT-xSBT ceramics showed a PZT phase and new phase in the compositions with 0.1 ≤ x ≤ 0.3, while a mainly new phase was observed in the compositionwith x=0.5. The tetragonality (c/a) of PZT phase decreasedwith increasing in SBT content up to x = 0.3. SEM micrographs of the sample surface showed equiaxed grains of the PZT phase and irregularly-shaped grains of the new phase in samples with 0.1 ≤ x ≤ 0.3. The 0.5PZT-0.5SBT sample showed mainly irregularly-shaped grains of the new phase. The ferroelectric properties of these samples showed that the addition of small amounts of SBT (x = 0.1) into PZT increased the remanent polarization. Copyright © 2013 Taylor & Francis Group, LLC.