Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation

© 2014 Elsevier Ltd. All rights reserved. A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carbo...

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Main Authors:	Funfuenha,W., Phakhodee,W., Pattarawarapan,M.
Format:	Article
Published:	Elsevier Limited 2015
Subjects:	Drug Discovery Organic Chemistry Biochemistry
Online Access:	http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84906084159&origin=inward http://cmuir.cmu.ac.th/handle/6653943832/38759
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Institution:	Chiang Mai University

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spelling	th-cmuir.6653943832-387592015-06-16T07:54:09Z Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation Funfuenha,W. Phakhodee,W. Pattarawarapan,M. Drug Discovery Organic Chemistry Biochemistry © 2014 Elsevier Ltd. All rights reserved. A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carboxyl group(s), followed by nucleophilic displacement of the remained chloride(s) in aqueous media under microwave irradiation. Novel C2-symmetrical tripodal ligands were afforded in good yields and purities under short reaction time with simple work-up, which are potentially useful as structural directing units in metal-organic frameworks. 2015-06-16T07:54:09Z 2015-06-16T07:54:09Z 2014-01-01 Article 00404020 2-s2.0-84906084159 10.1016/j.tet.2014.06.127 http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84906084159&origin=inward http://cmuir.cmu.ac.th/handle/6653943832/38759 Elsevier Limited
institution	Chiang Mai University
building	Chiang Mai University Library
country	Thailand
collection	CMU Intellectual Repository
topic	Drug Discovery Organic Chemistry Biochemistry
spellingShingle	Drug Discovery Organic Chemistry Biochemistry Funfuenha,W. Phakhodee,W. Pattarawarapan,M. Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
description	© 2014 Elsevier Ltd. All rights reserved. A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carboxyl group(s), followed by nucleophilic displacement of the remained chloride(s) in aqueous media under microwave irradiation. Novel C2-symmetrical tripodal ligands were afforded in good yields and purities under short reaction time with simple work-up, which are potentially useful as structural directing units in metal-organic frameworks.
format	Article
author	Funfuenha,W. Phakhodee,W. Pattarawarapan,M.
author_facet	Funfuenha,W. Phakhodee,W. Pattarawarapan,M.
author_sort	Funfuenha,W.
title	Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
title_short	Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
title_full	Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
title_fullStr	Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
title_full_unstemmed	Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
title_sort	facile and efficient synthesis of c2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
publisher	Elsevier Limited
publishDate	2015
url	http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84906084159&origin=inward http://cmuir.cmu.ac.th/handle/6653943832/38759
_version_	1681421531787296768

Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation

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