Flame-spray-made Zn-In-O alloyed nanoparticles for NO<inf>2</inf> gas sensing

• Main Authors: Samerjai T., Channei D., Khanta C., Inyawilert K., Liewhiran C., Wisitsoraat A., Phokharatkul D., Phanichphant S.
• Format: Journal
• Published: 2017
• Online Access: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84964987461&origin=inward; http://cmuir.cmu.ac.th/jspui/handle/6653943832/41517
• Institution: Chiang Mai University

© 2016 Elsevier B.V. All rights reserved. In this work, Zn-In-O nanoparticles with different Zn metallic contents (100·Zn/(Zn + In)) were produced by one-step flame spray pyrolysis technique and systematically characterized for NO 2 sensing. Structural characterizations by x-ray diffraction, transmission and scanning electron microscopy indicated that Zn and In form solid-solution oxide with smaller particle size and lower crystallinity compared with undoped ZnO and In 2 O 3 ones. In addition, energy-dispersive and X-ray photoemission spectroscopic analyses revealed that materials prepared with Zn content of 25% and 33% were In-rich oxides while those prepared with Zn contents of 40% and 50% were actually Zn-rich oxides. From gas-sensing measurement, only Zn-In-O sensors with the 50% input Zn content showed improved NO 2 response while other Zn-In-O sensors displayed inferior performances compared with undoped In 2 O 3 sensors. The roles of Zn content on NO 2 -sensing mechanisms of Zn-In-O sensor were explained based on particle/grain size and doping effects of solid-solution oxide. The Zn-In-O oxide with 50% input Zn content exhibited the optimal sensor response of 1476 to 5 ppm NO 2 at 250 °C. In addition, it still had good responses of 17 to low NO 2 concentrations of 0.125 ppm and good selectivity against NO, H 2 , H 2 S and CO. Therefore, the flame-made Zn-In-O sensor is another promising candidate for sensitive and selective NO 2 detections.