Ph<inf>3</inf>P-I<inf>2</inf> mediated aryl esterification with a mechanistic insight
© 2016 Elsevier Ltd. All rights reserved. In order to better understand the reaction mechanism and to obtain optimal conditions, the Ph 3 P-I 2 /Et 3 N mediated aryl esterification reaction was thoroughly investigated. Using a specific reagent addition sequence, the reaction proceeds remarkably well...
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th-cmuir.6653943832-418862017-09-28T04:23:54Z Ph<inf>3</inf>P-I<inf>2</inf> mediated aryl esterification with a mechanistic insight Phakhodee W. Duangkamol C. Pattarawarapan M. © 2016 Elsevier Ltd. All rights reserved. In order to better understand the reaction mechanism and to obtain optimal conditions, the Ph 3 P-I 2 /Et 3 N mediated aryl esterification reaction was thoroughly investigated. Using a specific reagent addition sequence, the reaction proceeds remarkably well especially with acidic substrates. 31 P NMR studies revealed that the formation of an aryloxyphosphonium salt is crucial in governing the reaction path toward the formation of phenolic esters. 2017-09-28T04:23:54Z 2017-09-28T04:23:54Z 2016-05-11 Journal 00404039 2-s2.0-84979486626 10.1016/j.tetlet.2016.03.105 https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84979486626&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/41886 |
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© 2016 Elsevier Ltd. All rights reserved. In order to better understand the reaction mechanism and to obtain optimal conditions, the Ph 3 P-I 2 /Et 3 N mediated aryl esterification reaction was thoroughly investigated. Using a specific reagent addition sequence, the reaction proceeds remarkably well especially with acidic substrates. 31 P NMR studies revealed that the formation of an aryloxyphosphonium salt is crucial in governing the reaction path toward the formation of phenolic esters. |
| format |
Journal |
| author |
Phakhodee W. Duangkamol C. Pattarawarapan M. |
| spellingShingle |
Phakhodee W. Duangkamol C. Pattarawarapan M. Ph<inf>3</inf>P-I<inf>2</inf> mediated aryl esterification with a mechanistic insight |
| author_facet |
Phakhodee W. Duangkamol C. Pattarawarapan M. |
| author_sort |
Phakhodee W. |
| title |
Ph<inf>3</inf>P-I<inf>2</inf> mediated aryl esterification with a mechanistic insight |
| title_short |
Ph<inf>3</inf>P-I<inf>2</inf> mediated aryl esterification with a mechanistic insight |
| title_full |
Ph<inf>3</inf>P-I<inf>2</inf> mediated aryl esterification with a mechanistic insight |
| title_fullStr |
Ph<inf>3</inf>P-I<inf>2</inf> mediated aryl esterification with a mechanistic insight |
| title_full_unstemmed |
Ph<inf>3</inf>P-I<inf>2</inf> mediated aryl esterification with a mechanistic insight |
| title_sort |
ph<inf>3</inf>p-i<inf>2</inf> mediated aryl esterification with a mechanistic insight |
| publishDate |
2017 |
| url |
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84979486626&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/41886 |
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1681422085284429824 |