Enhancement in Thermoelectric Properties of Cubic Ge<inf>2</inf>Sb<inf>2</inf>Te<inf>5</inf> Thin Films by Introducing Structural Disorder
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Thermoelectric performances are usually enhanced by minimizing the thermal conductivity of materials, either by introducing superlattice structures or nanostructuring. Here, a new approach to performance enhancement, based on Seebeck coefficie...
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| Main Authors: | , , , |
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| Format: | Journal |
| Published: |
2017
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| Online Access: | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84995877861&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/42058 |
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| Institution: | Chiang Mai University |
| Summary: | © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Thermoelectric performances are usually enhanced by minimizing the thermal conductivity of materials, either by introducing superlattice structures or nanostructuring. Here, a new approach to performance enhancement, based on Seebeck coefficient improvement, is presented for Ge 2 Sb 2 Te 5 thin films. The electron temperature was controlled by using pulsed direct current (DC) plasma power, and the resulting structural disorder of the cubic crystalline phase enhanced the Seebeck coefficients, as supported by molecular orbital calculations. Our results demonstrate a room-temperature Seebeck coefficient of 190.8μVK -1 for 200nm films deposited on glass. That′s a disorder! Here, a new approach to thermoelectric performance enhancement, based on Seebeck coefficient improvement, is presented for Ge 2 Sb 2 Te 5 thin films. The electron temperature was controlled by using pulsed direct current (DC) plasma power, and the resulting structural disorder of the cubic crystalline phase enhanced the Seebeck coefficients, as supported by molecular orbital calculations. Our results demonstrate a room-temperature Seebeck coefficient of 190.8μVK -1 for 200nm films deposited on glass. |
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