Study of the structures and physical properties of calcium borophosphate glass containing transition metal oxides

• Main Authors: Thiemsorn W., Tungyai T., Hessenkemper H.
• Format: Book Series
• Published: 2017
• Online Access: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84958212600&origin=inward; http://cmuir.cmu.ac.th/jspui/handle/6653943832/42395
• Institution: Chiang Mai University

© 2016 Trans Tech Publications, Switzerland. This research objected to study the effects of CeO 2 , Sb 2 O 3 and CoO on the structures and properties of calcium borophosphate glass (CBF) in ternary system 0.42CaO-0.06B2O 3 -0.52P 2 O 5 . The batches were melted at 1200 °C with 5 °C/min for 1 h in an electric furnace. The melts were regular bulk formed by pouring into a stainless mold and were immediately transferred to an annealing lehr at 550 °C for 2 h for testing the properties. The structures and physical properties were investigated. The results showed that all doped CBF glass were completely melted representing only one broad peak in XRD patterns. The structural observations revealed the major units are cross-linking B-O-P and B-O-B triangle and B-O-B tetrahedral units. The dense packing of structural or the shorter phosphate chain length and whether the branching group were achieved as the series CeO 2 > Sb 2 O 3 CoO. The density, refractive index, glossy, Abbe number increased slightly with increasing of transition oxide concentrations as the series CeO 2 > Sb 2 O 3 CoO. The microhardness also increased with increasing the concentration of transition oxides as the series CeO 2 < Sb 2 O 3 < CoO due to CoO act as glass-network formers stronger than Sb2O 3 and CeO 2 .