Tuning the band gap of ZnO thin films by Mg doping
© 2016 Trans Tech Publications, Switzerland. Structural, morphological, optical and electrical properties of magnesium (Mg) doped zinc oxide (ZnO) films were prepared by the ultrasonic spray pyrolysis technique on a microscope glass substrate, and have been studied in terms of the Mg doping content....
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| Main Authors: | , , , , , , |
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| Format: | Book Series |
| Published: |
2017
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| Online Access: | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84969921352&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/42484 |
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| Institution: | Chiang Mai University |
| Summary: | © 2016 Trans Tech Publications, Switzerland. Structural, morphological, optical and electrical properties of magnesium (Mg) doped zinc oxide (ZnO) films were prepared by the ultrasonic spray pyrolysis technique on a microscope glass substrate, and have been studied in terms of the Mg doping content. The precursor solutions of Mg doped ZnO films were prepared from zinc acetate dihydrate (Zn(CH 3 OO) 2 ·2H 2 O) and magnesium acetate tetrahydrate (CH 3 COO) 2 Mg·4H 2 O) as dopant. The compositions of these solutions were fixed at 0.02 M of Zn(CH 3 OO) 2 .2H 2 O and the atomic percentage ratio of Mg/Zn varied from 0 to 20 atomic %. The XRD patterns of all films showed ZnO hexagonal wurtzite structure and the morphology showed homogeneous structure/texture being pinhole-free with added Mg content. It was found that Mg2+ ions did not change conductivity of ZnO films due to the partial substitution of Zn2+ ion with the same valence Mg2+ ion. For optical properties, all films showed high transmittance over 80% and absorbance around 0.01 in the visible and near infrared regions. Moreover, the Mg dopant affects the shift of the absorption edge in the transmittance spectra of the films to a lower wavelength in the ultraviolet region and increases the band gap of the samples. |
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