The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives
© 2016 The Royal Society of Chemistry. A series of 1,1′-bis(sulfonyl)ferrocene compounds were produced via the 1,1′-bis(sulfonate)ferrocene ammonium salt. This compound can be readily converted to 1,1′ bis(sulfonylchloride)ferrocene. By varying stoichiometry and reaction times, both mono- and bis-su...
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th-cmuir.6653943832-426072017-09-28T04:28:05Z The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives Chanawanno K. Holstrom C. Crandall L. Dodge H. Nemykin V. Herrick R. Ziegler C. © 2016 The Royal Society of Chemistry. A series of 1,1′-bis(sulfonyl)ferrocene compounds were produced via the 1,1′-bis(sulfonate)ferrocene ammonium salt. This compound can be readily converted to 1,1′ bis(sulfonylchloride)ferrocene. By varying stoichiometry and reaction times, both mono- and bis-sulfonamide derivatives can be synthesized. All new compounds presented in this report have been structurally characterized. The structures of the bis-sulfonamide systems are similar to the well-studied bis(amide) ferrocene compounds. Intermolecular hydrogen bonding is observed, typically between NH and SO groups of neighboring sulfonamides. However in the bis(GABA) derivative, intermolecular NH to CO hydrogen bonding interactions are present. 2017-09-28T04:28:05Z 2017-09-28T04:28:05Z 2016-01-01 Journal 14779226 2-s2.0-84987778387 10.1039/c6dt02669a https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84987778387&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/42607 |
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© 2016 The Royal Society of Chemistry. A series of 1,1′-bis(sulfonyl)ferrocene compounds were produced via the 1,1′-bis(sulfonate)ferrocene ammonium salt. This compound can be readily converted to 1,1′ bis(sulfonylchloride)ferrocene. By varying stoichiometry and reaction times, both mono- and bis-sulfonamide derivatives can be synthesized. All new compounds presented in this report have been structurally characterized. The structures of the bis-sulfonamide systems are similar to the well-studied bis(amide) ferrocene compounds. Intermolecular hydrogen bonding is observed, typically between NH and SO groups of neighboring sulfonamides. However in the bis(GABA) derivative, intermolecular NH to CO hydrogen bonding interactions are present. |
| format |
Journal |
| author |
Chanawanno K. Holstrom C. Crandall L. Dodge H. Nemykin V. Herrick R. Ziegler C. |
| spellingShingle |
Chanawanno K. Holstrom C. Crandall L. Dodge H. Nemykin V. Herrick R. Ziegler C. The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives |
| author_facet |
Chanawanno K. Holstrom C. Crandall L. Dodge H. Nemykin V. Herrick R. Ziegler C. |
| author_sort |
Chanawanno K. |
| title |
The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives |
| title_short |
The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives |
| title_full |
The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives |
| title_fullStr |
The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives |
| title_full_unstemmed |
The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives |
| title_sort |
synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives |
| publishDate |
2017 |
| url |
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84987778387&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/42607 |
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