Effect of gold nanoparticles on lead zinc niobate–barium titanate structure by X-ray absorption spectroscopy

• Main Authors: Phakkhananan Pakawanit, Rattikorn Yimnirun, Yongyut Laosiritaworn, Kanokwan Kanchiang
• Format: Journal
• Published: 2018
• Subjects: Materials Science; Agricultural and Biological Sciences; Arts and Humanities
• Online Access: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85037692314&origin=inward; http://cmuir.cmu.ac.th/jspui/handle/6653943832/43476
• Institution: Chiang Mai University

© 2017 Taylor & Francis Group, LLC. The 0.93PZN-0.07BT ceramics containing 0.5 wt% AuNPs sintering was carried out for 3–5 h at various temperatures ranging from 1100 to 1150°C. The effect of AuNPs on 0.93PZN-0.07BT local structure and dielectric properties were investigated. The Au K-edge XANES spectrum indicated that AuNPs are not substituted into 0.93PZN-0.07BT structure. The dielectric constants and dielectric loss of 0.93PZN-0.07BT ceramics containing 0.5 wt% AuNPs after sintering at 1050°C for 3–5 h are higher and lower than that of 0.93PZN-0.07BT ceramics without AuNPs after sintering at 1100°C for 3–5 h, respectively, which can be described by assuming the connectivity series between the ceramics and the metal phases. In addition, Curie temperature shifting of 0.93PZN-0.07BT ceramics containing 0.5 wt% AuNPs due to the higher degree of chemical heterogeneity caused by the AuNPs addition. Therefore, the including of AuNPs into 0.93PZN-0.07BT ceramics can be improving dielectric properties with lower temperature and shorter time in sintering process.