CoTiO<inf>3</inf>/Ag<inf>3</inf>VO<inf>4</inf> composite: A study on the role of CoTiO<inf>3</inf> and the active species in the photocatalytic degradation of methylene blue

• Main Authors: Kanlayawat Wangkawong, Sukon Phanichphant, Doldet Tantraviwat, Burapat Inceesungvorn
• Format: Journal
• Published: 2018
• Subjects: Agricultural and Biological Sciences
• Online Access: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84930941838&origin=inward; http://cmuir.cmu.ac.th/jspui/handle/6653943832/44195
• Institution: Chiang Mai University

© 2015 Elsevier Inc. The role of CoTiO < inf > 3 < /inf > and the possible active species in the methylene blue (MB) degradation over the visible-light-driven CoTiO < inf > 3 < /inf > /Ag < inf > 3 < /inf > VO < inf > 4 < /inf > catalyst have firstly been investigated in this work. CoTiO < inf > 3 < /inf > is found to play important roles in enhancing the visible light-harvesting ability of the composite and increasing electron-hole separation efficiency due to the hybrid effect between Ag < inf > 3 < /inf > VO < inf > 4 < /inf > and CoTiO < inf > 3 < /inf > . The indirect probe experiments reveal that CoTiO < inf > 3 < /inf > /Ag < inf > 3 < /inf > VO < inf > 4 < /inf > heterostructure provides large amount of active species, therefore a high photocatalytic activity could be obtained. The results clearly suggest that the photocatalytic MB degradation over this hybrid catalyst is mainly governed by direct hole oxidation.