Synthesis, processing and tensile testing of a poly(l -lactide-co-caprolactone) monofilament fiber for use as an absorbable surgical suture
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. A poly(l-lactide-co-caprolactone), P(LL-co-CL), 75:25 mol % copolymer was synthesized via the bulk ring-opening copolymerization of l-lactide (LL) and ε-caprolactone (CL) at 130 °C for 48 hrs. The P(LL-co-CL) copolymer obtained was characteriz...
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| Main Authors: | , , , , , |
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| Format: | Journal |
| Published: |
2018
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| Subjects: | |
| Online Access: | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84940121926&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/44672 |
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| Institution: | Chiang Mai University |
| Summary: | © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. A poly(l-lactide-co-caprolactone), P(LL-co-CL), 75:25 mol % copolymer was synthesized via the bulk ring-opening copolymerization of l-lactide (LL) and ε-caprolactone (CL) at 130 °C for 48 hrs. The P(LL-co-CL) copolymer obtained was characterized in terms of its molecular weight (GPC), copolymer composition ( < sup > 1 < /sup > H-NMR), monomer sequencing ( < sup > 13 < /sup > C-NMR) and thermal properties (DSC, TGA). For processing, the P(LL-co-CL) was melt spun into a monofilament fiber with fast cooling and minimal draw in order to produce an as-spun fiber that was largely amorphous and unoriented. This enabled the required oriented semi-crystalline morphology to be gradually built into the as-spun fiber in a series of controlled off-line annealing and hot-drawing steps. The final fiber, which combined sufficient tensile strength with flexibility for use as a suture material, exhibited a stress and strain at break of 344 MPa and 70%, respectively. |
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